Skip to main content Accessibility help

Lithium-Iodine Intercalation in The Ferroelectric Layered Compound Bi4Ti3O12-x

  • T. Kijima (a1), S. Kimura (a1), Y. Kawahara (a1), K. Ohe (a1), M. Yada (a1) and M. Machida (a1)...


The reaction of Bi4Ti3O12-x with lithium iodide under an atmosphere of iodine at 400°C was found to afford a novel intercalation compound Lil3Bi4Ti3O11. The brownish red bismuth titanate is monoclinic with the lattice parameters of a=5.7417(2), b=5.4016(2), c=36.787(1) Å and ß=88.93(1) deg. The pathway to the new intercalation compound is proposed on the basis of X-ray, XPS, SEM and compositional observations.



Hide All
1. Xiang, X. D., Mckernan, S., Vareka, W. A., Zettl, A., Corkill, J. L, Barbee, T. W. III and Cohen, M. L., Nature 348, 145 (1990).
2. Xiang, X. D., Zettl, A., Vareka, W. A., Corkill, J. L, Barbee, T. W. II and Cohen, M. L., Phys. Rev. B 43, 11496 (1991).
3. Xiang, X. D., Vareka, W. A., Zettl, A., Corkill, J. L and Cohen, M. L., Phys. Rev. Lett. 68(1992), 530.
4. Scarfe, D. P., Bhavaraju, S. and Jacobson, A. J., Chem. Commun. 313 (1998)
5. Kumakura, H., Ye, J., Shimoyama, J., Kitaguchi, H., and Togano, K., J. J. Appl. Phys. 32, L894 (1993).
6. Choy, J., Park, N., Hwang, S., and Kim, Y., Synth. Metal. 71, 1551 (1995).
7. Muraoka, Y., Nagoshi, M., Morioka, Y., Kikuchi, M., Hiraga, K., Kobayashi, N. and , Shono, Physica C 263, 193(1996).
8. Choy, J., Park, N., Hwang, S., and Kim, D., J. Am. Chem. Soc. 116, 11564(1994).
9. Kijima, T., Sushida, H., Yada, M., and Machida, M., J. Solid State Chem. in press.
10. Dorrian, J. F., Newnham, R. E., Smith, D. K., Kay, M. I., Ferroelectrics 3, 17 (1971).
11. Aurivillius, B., Arkiv Kemi,1,463 (1949);1,499 (1949);2, 519 (1950).


Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed