Hostname: page-component-84b7d79bbc-g7rbq Total loading time: 0 Render date: 2024-07-30T11:12:25.701Z Has data issue: false hasContentIssue false

Laser Deposition of Molybdenum Oxide Thin Films From Organometallic Precursors

Published online by Cambridge University Press:  21 February 2011

Kurt A. Olson
Affiliation:
International Business Machines Corp., East Fishkill Facility, Route 52, Hopewell Junction, NY 12533–0999
Glenn L. Schrader
Affiliation:
Iowa State University, Dept. of Chemical Engineering, 231 Sweeney Hall, Ames, IA 50011–2230
Get access

Abstract

Thin films of crystalline molybdenum oxides were formed on silicon surfaces by laser deposition. An ArF excimer laser was used to photodissociate molybdenum hexacarbonyl in an oxygen-containing ambient. Normal incidence of the laser led to the formation of very thin (< 1000 Å) films of crystalline MO4O11. The films were characterized by color, SEM, Raman spectroscopy, and X-ray diffraction.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Kihlborg, L. Arkiv Kemi 21, 471 (1963).Google Scholar
[2] Gilgen, H. H., Cacouris, T., Shaw, P. S., Krchnavek, R. R., Osgood Appl. Phys. B 42, 55 (1987).Google Scholar
[3] Flynn, D. K., Steinfeld, J. I., Sethi, D. S. J. Appl. Phys. 59(11), 3914 (1986).Google Scholar
[4] Solanki, R., Boyer, P. K., Mahan, J. E., Collins, G. J. Appl. Phys, Lett. 38(7), 572 (1981).Google Scholar
[5] Kovall, G. A., Matthews, J. C., Solanki, R. in Photon. Beam. and Plasma Stimulated Chemical Processes at Surfaces, edited by Donnelly, V. M., Herman, I. P., Hirose, M. (Mater. Res. Soc. Proc. 60, Pittsburgh, PA 1987) p. 145.Google Scholar
[6] Mayer, T. M., Fisanick, G. J., Eichelberger, T. S. IV J. Appl Phys 53(12), 8462 (1982).Google Scholar
[7] Gluck, N. S., Wolga, G. J., Bartosch, C. E., Ho, W., Ying, Z. J. Appl. Phys. 61(3), 998 (1987).Google Scholar
[8] Gupta, P. K., Chopra, K. L. Appl. Phys. Lett. 51(19), 1527 (1987).Google Scholar
[9] Carcia, P. F., McCarron, E. M. III Thin Solid Films 155, 53 (1987).Google Scholar
[10] Saito, Y., Kaito, C., Naiki, T. J.Cryst. Growth 79, 436 (1986).Google Scholar
[11] Miyata, N., Akiyoshi, S. J. Appl. Phys. 54(8), 1651 (1985).Google Scholar
[12] Tracy, C. E., Benson, D. K. J. Vac. Sci. Technol. A 4(5), 2377 (1986).Google Scholar