Skip to main content Accessibility help
×
Home

Ionic Complexes Of Conjugated Oligoquinolines

  • Ashok S. Shetty (a1) and Samson A. Jenekhe (a1)

Abstract

Single crystal X-ray structures of salt complexes of oligoquinoline, 2,2'-bis(4- phenylquinoline)-1,4-phenylene (4), with p-toluenesulfonic acid, trifluoromethanesulfonic acid and a laser dye, Sulforhodamine 101 hydrate have been determined and used to study the effects of molecular packing on physical and photophysical properties of conjugated oligomer and polymers. UV-vis and emission spectra of thin films of the oligoquinoline-p-toluenesulfonate complex were also performed. These results indicate that they form an intermolecular charge-transfer complex. These complexes serve as models of quarternized polyquinolines such as the self-assembled bilayer films of polyquinoline and polystyrenesulfonic acid.

Copyright

References

Hide All
1. Bredas, J. L., Chance, R. R., Eds. Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics; Kluwer Academic Publishers; Dordrecht, the Netherlands, 1990.
2. Agrawal, A. K., Jenekhe, S. A.,Chem. Mater., 8, 579 (1996).
3. Agrawal, A. K., Jenekhe, S. A., Macromolecules, 26, 895 (1993).
4. Abkowitz, M. A., Stolka, M., Antoniadis, H., Agrawal, A. K., Jenekhe, S. A., Solid State Commun., 83, 937 (1992).
5. Agrawal, A. K., Jenekhe, S. A., Vanherzeele, H., Meth, J. S., J. Phys. Chem., 96, 2837 (1992).
6. Jenekhe, S. A., Zhang, X., Chen, X. L., Choong, V.-E., Gao, Y., Hsieh, B. R., Chem. Mater., 9, 409 (1997).
7. Ferreira, M. and Rubner, M. F., Macromolecules, 28, 7107 (1995)
8. Decher, G.; Hong, J. D.; Schmitt, J.; Thin Solid Films, 210, 831 (1992)
9. Y, Lvov.; G., Decher.; H, Mohwald.; Langmuir, 9, 520 (1993)
10. Tian, J., Wu, C.-C., Thomson, M.E., Sturn, J. C., Register, R. A., Marsella, M. J., and Swager, T. M., Adv. Mater., 7, 395 (1995)
11. Fou, A. C., Onitsuka, O., Ferrera, M., and Rubner, M. F., J. Appl. Phys., 79, 7501 (1996)
12. Mao, G., Tsao, Y.. Tirrell, M., and Davis, H. T., Langmuir, 9, 3461 (1993)
13. Yi, S., Shetty, A.S. and Jenekhe, S.A., manuscript in preparation.
14. Shetty, A.S., Liu, E.B., Lachicotte, R.J. and Jenekhe, S.A., manuscript in preparation.
15. (a) Shetty, A.S., Zhang, J., Moore, J. S., J.Am.Chem. Soc. 118, 1019 (1996) (b) J.H. Williams, Acc. Chem. Res. 26, 593 (1993) and references therein.

Ionic Complexes Of Conjugated Oligoquinolines

  • Ashok S. Shetty (a1) and Samson A. Jenekhe (a1)

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed