Hostname: page-component-8448b6f56d-t5pn6 Total loading time: 0 Render date: 2024-04-18T17:03:46.514Z Has data issue: false hasContentIssue false

Ion Beam Modification of PVDC and Pe Polymers

Published online by Cambridge University Press:  21 February 2011

A. L. Evelyn
Affiliation:
Center for Irradiation of Materials, Alabama A'M University, Normal AL
D. Ila
Affiliation:
Center for Irradiation of Materials, Alabama A'M University, Normal AL
J. Fisher
Affiliation:
Center for Irradiation of Materials, Alabama A'M University, Normal AL
D. B. Poker
Affiliation:
Center for Irradiation of Materials, Alabama A'M University, Normal AL Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN.
Get access

Abstract

The electronic and nuclear stopping effects produced by MeV ion bombardment in polyvinylidine chloride (PVDC) and polyethylene (PE) are separated by stacking thin films of the polymers. The resulting multi-layer laminates of each polymer were bombarded with 3.5 MeV alpha particles. The energy of the incident ions was selected, using TRIM, such that the first layers experienced most of the effects of the electronic energy deposited and the last layers received most of the effects of the nuclear stopping power. The changes in the conductance and the chemical structure of each layer were measured by direct resistivity measurements and Raman microprobe analysis.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Ila, D., Evelyn, A. L. and Jenkins, G. M., Ion Beam induced Carbonization of Partially Cured Phenolic Resin, Nucl. Instr. ' Meth. B91, 580 (1994).Google Scholar
2 Ila, D., Evelyn, A. L and Jenkins, G. M., Ion Beam Induced Graphitization of Phenolformaldehyde, Mat. Res. Soc. Symp Proc. Vol. 321, 441 (1994).Google Scholar
3 Evelyn, A. L., Ila, D. and Jenkins, G. M., RBS and Raman Spectroscopy Study of Heat Treatment Effect on Phenolformaldehyde Resin, Nucl. Instr. ' Method, in Phys. Research B85, 861 (1994).Google Scholar
4 Venkatensan, T., Levi, R., Banwell, T. C., Tombrello, T., Nicolet, M., Hamm, R. and Meixner, A. E. in Ion Beam Processes in Advanced Electronic Materials and Device Technology, edited by Eisen, F. H., Sigmon, T. W. and Appleton, B. R. (Mat. Res. Soc. Symp. Proc. 45, Pittsburgh, PA, 1985) p. 189.Google Scholar
5 Sofield, C. J., Sugden, S., Bedell, C. J., Graves, P. R. and Bridwell, L. B., Nucl. Instr. and Meth. B 67, 432(1992).Google Scholar
6 Wang, Y. Q., Giedd, R. E. and Bridwell, L. B., Nucl. Instr. and Meth. B 79, 659 (1993).Google Scholar
7 Dresselhaus, M. S., Wasserman, B. and Wnek, G.E., Mat. Res. Soc. Symp. Proc. 27, 413 (1983).Google Scholar
8 Calcagno, L. and Foti, G., Nucl. Instr. and Meth. B 59/60, 1153 (1991).Google Scholar
9 Wang, Y., Mohite, S.S., Bridewell, L.B., Giedd, R.E. and Schofield, C.J., J. Mat. Res. 8, 388 (1993).Google Scholar
10 Jenkins, G. M., Ila, D. and Williams, E. K. in Polymer/Inorganic Interfaces, edited by Opila, R. L., Boerio, F. J. and Czanderna, A. W. (Mat. Res. Soc. Symp Proc. 304, Pittsburgh, PA, 1993) pp. 173177.Google Scholar
11 Davenas, J. and XU, X. L., Relation Between Structure and Electronic Properties of Ion Irradiated Polymers, Nucl. Instr. ' Meth. B39 754 (1989).Google Scholar
12 Ila, D., Evelyn, A. L. and Qian, Y., Proc. Mat. Res. Soc. Symp. Vol. 338, 613 (1994).Google Scholar
13 Ila, D., Evelyn, A. L. and Jenkins, G. M., Nucl. Instr. ' Meth. in Phys Res B91 580 (1994).Google Scholar
14 Ziegler, J. F., Biersack, J. P. and Littmark, U., The Stopping and Range of Ions in Solids (Pergamon Press Inc., New York, 1985).Google Scholar
15 Sofield, C. J., Sugden, S., Bedell, C. J., Graves, P. R. and Bridwell, L. B., Nucl. Instr. ' Meth. B67, (1992) 432.Google Scholar
16 Jeoung, H-S. and White, R.C., Mat. Res. Soc. Symp. Proc. Vol. 235, (1991) 787.Google Scholar
17 lia, D., et al, Ion Beam Enhanced Electrical Conductivity in Polymers, Nucl. Instr. and Meth. B(1995). In print.Google Scholar
18 Jenkins, G. M. and Kawamura, K., Polymeric Carbons - Carbon Fiber, Glass and Char (Cambridge University Press, 1976).Google Scholar
19 Vidano, R. and Fischbach, D.B., J. Am. Chem. Soc. 61, 13(1978).Google Scholar