Hostname: page-component-8448b6f56d-mp689 Total loading time: 0 Render date: 2024-04-19T07:36:44.603Z Has data issue: false hasContentIssue false
  • English
  • Français

Intermediate Range Order in SixSe1−x Glasses*

Published online by Cambridge University Press:  25 February 2011

S. Susman ,
R. W. Johnson ,
D. L. Price  and
K. J. Volin
S. Susman
Affiliation:
Materials Science and Technology Division, Argonne National Laboratory, Argonne, IL 60439
R. W. Johnson
Affiliation:
Laboratory Graduate Participant, University of Chicago, Chicago, IL 60637
D. L. Price
Affiliation:
Materials Science and Technology Division, Argonne National Laboratory, Argonne, IL 60439
K. J. Volin
Affiliation:
Materials Science and Technology Division, Argonne National Laboratory, Argonne, IL 60439
Get access

Abstract

Six (chalcogen)1−x glasses represent a class of amorphous, binary, semiconducting solids of increasing theoretical and technological importance. In our laboratory, attention has been directed to these systems since they can form the basis of a remarkable series of fast ion conducting glasses. These vitreous materials are being considered as solid electrolytes for advanced electrochemical cells of high specific energy. For example, when stoichiometric SiS 2 is appropriately combined with Na2S, a Na-ion conducting glass results that has a room-temperature Na-ion conductivity that is several orders of magnitude greater than that of its oxide counterpart [1].The structures and defects present in these alkali-modified, ternary glasses are not known [2]. In fact, until recently, there has been a paucity of attention directed to the “simple” binary glass systems Si/S, Si/Se, and Si/Te. Therefore, four years ago, we began a systematic study of the structure and dynamics of Si xS1 SixSe1−x, and SixTe1−x covalent glasses. Of necessity, an interdisciplinary approach was adopted.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 61: Symposium P – Defects in Glasses , 1985 , 91
Copyright
Copyright © Materials Research Society 1986

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

*

Work supported by the U. S. Department of Energy, BES-Materials Sciences, under Contract W-31-109-Eng-38.

References

[1] Ribes, M., Barrau, B., and Souquet, J. L., J. Non-Crystalline Solids, 38–39, 271 (1980).Google Scholar
[2] Susman, S., Boehm, L., Volin, K. J., and Delbecq, C. J., Solid State Ionics, 5, 667 (1981).CrossRefGoogle Scholar
[3] Weiss, A. and Weiss, A., Z Naturforsch. 7B, 483 (1952). J. Peters and B. Krebs, Acta Cryst., B38, 1270 (1982).Google Scholar
[4] Weiss, A. and Weiss, A., Z. Naturforsch. 8B, 104 (1953).Google Scholar
[5] Tenhover, M., Hazle, M. A., and Grasselli, R. K., Phys. Rev. Lett. 51 404 (1983).Google Scholar
[6] Tenhover, M., Henderson, R. S., Lukco, D., Hazle, M. A., and Grasselli, R. K., Solid State Comm., 51, 455 (1984).Google Scholar
[7] Griffiths, J. E., Malyj, M., Espinosa, G. P., and Remeika, J. P., Phys. Rev. B. 30, 6978 (1984).Google Scholar
[8] Tenhover, M., Hazle, M. A., Grasselli, R. K., and Tompson, C. W., Phys. Rev. B. 28, 4608 (1983).Google Scholar
[9] Johnson, R. W., Susman, S., McMillan, J., and Volin, K. J., Materials Research Bull., to be published, January 1986.Google Scholar
[10] White, W. B., J. Non-Crystalline Solids, 49, 321 (1982).Google Scholar
[11] Johnson, R. W., Price, D. L., Susman, S., Morrison, T. I., Shenoy, G. K., and Arai, M., J. Non-Crystalline Solids, submitted.Google Scholar
[12] Johnson, R. W., Susman, S., and Price, D. L., J. Non-Crystalline Solids, 75, 57 (1985). R. W. Johnson, J. Non-Crystalline Solids, submitted.CrossRefGoogle Scholar
[13] Johnson, R. W., Ph.D., University of Chicago, in preparation. R. W. Johnson, S. Susman, D. L.Price, and K. J. Volin, Physics and Chem. of Glasses, to be submittedGoogle Scholar
[14] Moss, S. C. and Price, D. L. in “Physics of Disordered Materials,” Adler, D., Fritsche, H., and Ovshinsky, S. R., eds. Plenum Press, New York, 1985, pp. 77–95 Google Scholar
[15] Griffiths, J. E., Malyj, M., Espinosa, G. P., and Remeika, J. P., Solid State Comm., 53, 587 (1985)Google Scholar
[16] Carroll, P. G. and Lannin, J. S., Solid State Comm. 40, 81 (1981)Google Scholar