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Intercalation Of Layered V2O5 Xerogel With Polymers

Published online by Cambridge University Press:  15 February 2011

M. G. Kanatzidis ,
C.-G. Wu ,
Y.-J. Liu ,
D. C. DeGroot ,
J. L. Schindler ,
H. O. Marcy  and
C. R. Kannewurf
M. G. Kanatzidis
Affiliation:
Department of Chemistry and the Center of Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824
C.-G. Wu
Affiliation:
Department of Chemistry and the Center of Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824
Y.-J. Liu
Affiliation:
Department of Chemistry and the Center of Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824
D. C. DeGroot
Affiliation:
Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208
J. L. Schindler
Affiliation:
Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208
H. O. Marcy
Affiliation:
Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208
C. R. Kannewurf
Affiliation:
Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208
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Abstract

The intercalation properties of the layered V2O5 xerogel towards conductive polymers are described. The systems intercalated with polyaniline show post-intercalative redox polymerization caused by ambient oxygen to give products with enhanced conductivity. For the first time the role of oxygen in this intercalation reaction has been unequivocally identified. We also report the synthesis and some properties of a new intercalation compound in which the guest species is poly(ethylene oxide), an insulating polymer.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 233: Symposium U – Synthesis/Characterization and Novel Applications of Molecular Sieve Materials , 1991 , 183
Copyright
Copyright © Materials Research Society 1991

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References

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