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In-Plane Ferroelectricity in Strontium Titanate Thin Films

Published online by Cambridge University Press:  01 February 2011

K. F. Astafiev
Affiliation:
Ceramics Laboratory, Swiss Federal Institute of Technology, EPFL, 1015 Lausanne, Switzerland.
V. O. Sherman
Affiliation:
Ceramics Laboratory, Swiss Federal Institute of Technology, EPFL, 1015 Lausanne, Switzerland.
M. Cantoni
Affiliation:
Ceramics Laboratory, Swiss Federal Institute of Technology, EPFL, 1015 Lausanne, Switzerland.
A. K. Tagantsev
Affiliation:
Ceramics Laboratory, Swiss Federal Institute of Technology, EPFL, 1015 Lausanne, Switzerland.
N. Setter
Affiliation:
Ceramics Laboratory, Swiss Federal Institute of Technology, EPFL, 1015 Lausanne, Switzerland.
P. K. Petrov
Affiliation:
Centre of Physical Electronics and Materials, South Bank University, 103 Borough Road, London SE1 0AA, UK.
T. Kaydanova
Affiliation:
National Renewable Energy Laboratory, Golden, 1617 Cole Boulevard, CO 80401, USA.
D. S. Ginley
Affiliation:
National Renewable Energy Laboratory, Golden, 1617 Cole Boulevard, CO 80401, USA.
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Abstract

The results of structural and electrical characterizations of SrTiO3 thin films deposited onto LaAlO3 substrates by pulsed laser deposition technique are presented. The appearance of the ferroelectric phase in these films has been experimentally documented, the transition temperature being in the range of 90–120K. The hysteresis loops have been monitored in a wide temperature range by using thin film planar capacitors, the driving field being predominantly in the plane of the film. The switching properties of the films has been studied at low temperatures (∼25K) and well saturated loops have been observed with relatively low coercive field (<6kV/cm for 10μm gap). The presence of the imprint phenomenon has been also found at low temperatures.

The microstructure of the investigated SrTiO3 thin films has been studied by using a high resolution transmission electron microscope (TEM). It has been found that the annealed and as-deposited thin films, being of the same composition, have quite different microstructures. The difference observed in the polarization response of the films is related to that in their microstructure.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

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References

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