Hostname: page-component-7bb8b95d7b-nptnm Total loading time: 0 Render date: 2024-09-19T09:39:15.097Z Has data issue: false hasContentIssue false
  • English
  • Français

The Hydrothermal Synthesis of Layered Molybdenum Phosphates with Octahedral-Tetrahedral Layers

Published online by Cambridge University Press:  15 February 2011

Robert C. Haushalter  and
Linda A. Mundi
Robert C. Haushalter
Affiliation:
Exxon Research and Engineering Co., Rt. 22E, Annandale, NJ, 08801
Linda A. Mundi
Affiliation:
Exxon Research and Engineering Co., Rt. 22E, Annandale, NJ, 08801
Get access

Abstract

While we have prepared and structurally characterized over forty solids in the octahedral-tetrahedral framework molybdenum phosphate (MoPO) system, including molecules, 1-D polymers and 3-D materials, this paper will focus on the two dimensional layered MoPO's. Both covalently and H bonded layers will be discussed. Compounds covered include Na3[Mo2O4(HPO4)(PO4)]·2H2O, (Et2NH2)2[Mo4O8(PO4)4/2], Cs2Mo4P6O26, (4-phenylpyridie)2[Mo4O8(PO4)4/2], (cation)[Mo2O2(PO4)2(H2PO4)], with several different types of organic and inorganic cations, and (4-phenylpiperidine)4[Na2.5Mo6O15(H1.4PO4)4]·4H2O. These materials might provide a platform for the preparation of new types of pillared and intercalated inorganic solids.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 233: Symposium U – Synthesis/Characterization and Novel Applications of Molecular Sieve Materials , 1991 , 255
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Meier, W.M. and Olson, D.H., Atlas of Zeolite Structure Types, 2nd ed., (Butterworths, London, 1987).Google Scholar
2. Szostak, R., Molecular Sieves: Principles of Synthesis and Identification, (Van Nostrand, Reinhold, New York, 1989).Google Scholar
3. Occelli, M.L. and Robson, H.E., Zeolite Synthesis, (American Chemical Society, Washington, 1989).Google Scholar
4. Ruthven, D.M., Principles of Adsorption and Adsorption Processes, (Wiley, New York, 1984) p. 49 Google Scholar
5. Kuznicki, S.M., U.S. Patent No. 4 853 202 (1 August 1989)Google Scholar
6. Haushalter, R.C., Strohmaier, K.G., Lai, F.W., Science 246, 1289 (1989).Google Scholar
7. Mundi, L.A., Haushalter, R.C., Inorg. Chem. 30, 153, (1991).Google Scholar
8. King, H.E. Jr.,, Mundi, L.A., Strohmaier, K.G., Haushalter, R. C., J. Solid State Chem. (in press)Google Scholar
9. Mundi, L.A., Strohmaier, K.G., Haushalter, R.C., J. Am. Chem. Soc., 112. 8182 (1990).Google Scholar
10. Leclaire, A., Monier, J.C., Raveau, B., J. Solid State Chem., 48, 147 (1983); A. Leclaire, J.C. Monier, B. Raveau, J. Solid State Chem., 59, 301, (1985); A. Leclaire, M.M. Borel, A. Grandin, B. Raveau, J. Solid State Chem., U, 10, (1990); S.L. Wang, C.C. Wang, K.H. Lii, J. Solid State Chem., 74, 409 (1988); K.H. Lii, J.J. Chen, S.L. Wang, J. Solid State Chem., 78, 178, (1989); K.H. Lii, D.P. Goshorn, D.J. Johnston, R.C. Haushalter, J. Solid State Chem., 71, 131, (1987); K.H. Lii, C.J. O'Connor, R.C. Haushalter, Angew. Chem. Int. Ed. Eng. 26, 549 (1987); R.C.Haushalter, K.H. Lii, Acta Cryst., C43, 2036 (1987); R.C. Haushalter and F.W. Lai, J. Solid State Chem., 76. 218 (1988); R.C. Haushalter, F.W. Lai, J. Solid State Chem. 83, 202 (1989); R.C.Haushalter, F.W. Lai, Angew. Chem. Int. Ed. Eng., 101, 802 (1989).CrossRefGoogle Scholar
11. Haushalter, R. C., to be published.Google Scholar
12. Lii, K. H., Haushalter, R.C., J. Solid State Chem., 69, 320 (1987).Google Scholar
13. Mundi, L.A., Haushalter, R.C., Inorg. Chem., 29, 2879 (1990).Google Scholar
14. Mundi, L.A., Haushalter, R.C., submitted for publication.Google Scholar
15. Mundi, L.A., Haushalter, R. C., Inorg. Chem., 30, 153 (1991).CrossRefGoogle Scholar
16. Corcoran, E. W. Jr.,, Inorg. Chem., 29, 157, (1990).Google Scholar
17. Peascoe, R., Clearfield, A., submitted for publication.Google Scholar