Hostname: page-component-848d4c4894-mwx4w Total loading time: 0 Render date: 2024-06-24T04:22:49.246Z Has data issue: false hasContentIssue false
  • English
  • Français

Formation Mechanisms of Perovskite Pb(Ni1/3Nb2/3)O3 in Reaction-sintering Process

Published online by Cambridge University Press:  01 February 2011

Yi-Cheng Liou ,
Yi-Chen Huang  and
Chi-Ting Wu
Yi-Cheng Liou
Affiliation:
Department of Electronic Engineering, Kun-Shan University of Technology, Tainan Hsien 710, Taiwan, R.O.C.
Yi-Chen Huang
Affiliation:
Department of Electronic Engineering, Kun-Shan University of Technology, Tainan Hsien 710, Taiwan, R.O.C.
Chi-Ting Wu
Affiliation:
Department of Electronic Engineering, Kun-Shan University of Technology, Tainan Hsien 710, Taiwan, R.O.C.
Get access

Abstract

Formation mechanisms of perovskite Pb(Ni1/3Nb2/3)O3 (PNN) in the reaction-sintering process were investigated. Only the reflections of raw materials were detected at 400°C. For pellets heated to 500°C, pyrochlore phase Pb2Nb2O7 (P2N2) are found. Cubic Pb3Nb4O13 (P3N4) pyrochlore phase formed and became the main phase in pellets heated to 600°C. After being heated to 800°C, Pb3Nb2O8 (P3N2) pyrochlore phase formed in the pellets. As the pellets were heated to 900°C, the peak of NiNb2O6 columbite phase appeared. In pellets heated to 950°C, the weak peaks of PNN perovskite phase appeared. This means the perovskite phase formed at a temperature between 900°C and 950°C. As the pellets were heated to 1000°C, a large amount of PNN was formed and became dominant. The PbO, NiNb2O6 and Pb3Nb2O8 phases disappeared. The P3N4 content increased with temperature in pellets heated to 1050–1200°C. For pellets heated to 1250°C, the P3N4 content decreased significantly.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 848: Symposium FF – Solid-State Chemistry of Inorganic Materials V , 2004 , FF9.2
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bokov, V. A. and Myl'nikova, I. E., Sov. Phys.-Solid State 3 (3), 613 (1961).Google Scholar
2. Takahashi, S., Miyao, S., Yoneda, S. and Kuwabara, M., Jpn. J. Appl. Phys. 32 part 1 [9B], 4245 (1993).Google Scholar
3. Agranovskaya, A. I., Bull. Acad. Sci. USSR Phys. Ser. 1, 1271 (1960).Google Scholar
4. Veitch, L. C., BS Thesis, The Pennsylvania State University, 1983.Google Scholar
5. Swartz, S. L. and Shrout, T. R., Mater. Res. Bull. 17, 1245 (1982).Google Scholar
6. Liou, Y. C., Wu, L. and Liou, S. S., Jpn. J. Appl. Phys. 33 part 2 [9B], L1320(1994).Google Scholar
7. Kong, L. B. and Ma, J., Mater. Lett. 51, 95 (2001).Google Scholar
8. Liou, Y. C., Tseng, K. H. and Yu, C. H., Proceedings of the 2001 annual Conference of the Chinese Society for Materials Science, 23–24 November 2001, National Chung Hsing University, Taichung, Taiwan, P03–09.Google Scholar
9. Liou, Y. C., Tseng, K. H. and Yu, C. H., Proceedings of the 2001 annual Conference of the Chinese Society for Materials Science, 23–24 November 2001, National Chung Hsing University, Taichung, Taiwan, P03–17.Google Scholar
10. Liou, Y. C., Shih, C. Y. and Yu, C. H., Proceedings of the 2001 annual Conference of the Chinese Society for Materials Science, 23–24 November 2001, National Chung Hsing University, Taichung, Taiwan, P03–102.Google Scholar
11. Chen, J. H., Liou, Y. C. and Tseng, K. H., Jpn. J. Appl. Phys. 42 [1A], 175 (2003).Google Scholar
12. Liou, Y. C., Shih, C. Y. and Yu, C. H., Mater. Lett. 57, 1977 (2003).Google Scholar
13. Liou, Y. C., J. Electroceram. 12, 187 (2004).Google Scholar
14. Liou, Y. C., J. Electroceram. (2004) in press.Google Scholar
15. Liou, Y. C., J. Electroceram. (2004) in press.Google Scholar
16. Liou, Y. C. and Huang, Y. C., Proceedings of the 2003 annual Conference of the Chinese Society for Materials Science, 21–22 November 2003, Kun-Shan University of technology, Tainan Hsien, Taiwan.Google Scholar
17. Liou, Y. C., Chen, J. H. and Chuang, C. J., Proceedings of the 2003 annual Conference of the Chinese Society for Materials Science, 21–22 November 2003, Kun-Shan University of technology, Tainan Hsien, Taiwan.Google Scholar
18. Liou, Y. C., Chen, J. H. and Shih, Y. C., Proceedings of the 2003 annual Conference of the Chinese Society for Materials Science, 21–22 November 2003, Kun-Shan University of technology, Tainan Hsien, Taiwan.Google Scholar
19. Inada, M., Jpn. Natl. Tech. Rept. 27 [1], 95 (1977).Google Scholar
20. Lejeune, M. and Boilot, J. P., Ceram. Int., 8 [3], 99 (1982).Google Scholar
21. Kassarjian, M. P., Newnham, R. E. and Biggers, J. V., Am. Ceram. Soc. Bull. 64 [8], 1108 (1985).Google Scholar
22. Fu, S. L. and Chen, G. F., Ferroelectrics 82, 119 (1988).Google Scholar
23. Jenhi, M., EL Ghadraoui, E. H., Bali, H., EL Aatmani, M. and Rafiq, M., Eur. J. Solid Inorg. Chem. t. 35, 221 (1998).Google Scholar
24. Lu, C. H. and Huang, W. J., Cerm. Int. 22, 373 (1996).Google Scholar
25. Chen, S. Y., Wang, C. M. and Cheng, S. Y., Mater. Chem. & Phys. 49, 70 (1997).Google Scholar
26. Bhat, V. V., Rao, M. V. R. and Umarji, A. M., Mater. Res. Bull. 38, 1081 (2003).Google Scholar
27. Alberta, E. F. and Bhalla, A. S., Mater. Lett. 54, 47 (2002).Google Scholar
28. Lu, C. H. and Huang, W. J., Jpn. J. Appl. Phys. 38, part 1 [9B], 5478 (1999).Google Scholar