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Field-Scale Migration of 99Tc and 129I at the Nevada Test Site

Published online by Cambridge University Press:  17 March 2011

Qinhong Hu  and
David K. Smith
Qinhong Hu
Affiliation:
Chemical Biology and Nuclear Science Division, Lawrence Livermore National Laboratory 7000 East Avenue, MS L-231, Livermore, CA 94550, U.S.A
David K. Smith
Affiliation:
Chemical Biology and Nuclear Science Division, Lawrence Livermore National Laboratory 7000 East Avenue, MS L-231, Livermore, CA 94550, U.S.A
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Abstract

The groundwater at the Nevada Test Site (NTS) contains many long-lived radionuclides, including 99Tc (technetium) and 129I (iodine), as a result of 828 underground nuclear weapons tests conducted between 1951 and 1992. We synthesized a body of data collected on the distribution of 99Tc and 129I in groundwater to assess their migration at NTS, at field scales over distances of hundreds of meters and for durations up to forty years and under hydrogeologic conditions very similar to the proposed geological repository at Yucca Mountain. The results of our study show that Tc does not necessarily exist as a mobile and conservative species TcO4−, as has been commonly assumed. This conclusion is corroborated by recent in situ redox potential measurements, which show that groundwaters at multiple locations of the NTS are not oxidizing, and mobility of reduced Tc species (TcO2·nH2O) is greatly decreased. Speciation of iodine and its associated reactivity is also complex in the groundwater at the NTS, and its effect on the mobility of iodine should be the subject of future studies.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 824: Symposium CC – Scientific Basis for Nuclear Waste Management XXVIII , 2004 , CC7.7
Copyright
Copyright © Materials Research Society 2004

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References

1. Smith, D. K., Kersting, A. B., Thompson, J. L., and Finnegan, D. L., Scientific Basis for Nuclear Waste Management XXIV, Materials Research Society, 663, 1023–1032 (2001).Google Scholar
2. Smith, D. K., Finnegan, D. L., and Bowen, S. M., J. Environ. Radioactivity. 67, 35 (2003).Google Scholar
3. Lieser, K. H., and Bauscher, C. H.,Radiochim. Acta, 42, 205 (1987).Google Scholar
4. Buddemeier, R. W., Finkel, R. C., Marsh, K. V., Ruggieri, M. R., Rego, J. H., and Silva, R. J., Radiochim. Acta, 52/53, 275 (1991).Google Scholar
5.International Atomic Energy Agency (IAEA), The radiological situation at the atolls of Mururoa and Fangataufa: Inventory of radionuclides underground at the atolls, Technical Report, Vol. 3, Vienna (1998).Google Scholar
6. Finnegan, D. L., and Thompson, J. L., Laboratory and field studies related to radionuclide migration at the Nevada Test Site in support of the Underground Test Area Program and Hydrologic Resources Management Project, Los Alamos National Laboratory, Los Alamos, NM, LA-14042-MS (2003).Google Scholar
7. Sheppard, M., and Thibault, D. H., Appl. Geochem., 7, 265 (1992).Google Scholar
8. Bryant, E. A., The CAMBRIC migration experiment–A summary report, Los Alamos National Laboratory, Los Alamos, NM, LA-12335-MS (1992).Google Scholar
9. Wolfsberg, K., Sorption–desorption studies of Nevada Test Site alluvium and leaching studies of nuclear explosion debris, Los Alamos National Laboratory, Los Alamos, NM, LA-7216-MS (1978).Google Scholar