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Fabrication of (Cu,Ag)InSe2 Thin films by a Combination of Mechanochemical and Screen Printing/Sintering Processes

Published online by Cambridge University Press:  01 February 2011

Syuusuke Nomura
Affiliation:
t06m064@students.chem.ryukoku.ac.jp, Ryukoku University, Department of Materials chemistry, Seta, Otsu, 520-2194, Japan
Yoshihiro Matsuo
Affiliation:
twada@rins.ryukoku.ac.jp, Ryukoku University, Department of Materials Chemistry, Seta, Otsu, 520-2194, Japan
Takahiro Wada
Affiliation:
twada@rins.ryukoku.ac.jp, Ryukoku University, Department of Materials Chemistry, Seta, Otsu, 520-2194, Japan
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Abstract

We successfully prepared (Cu1-XAgx)InSe2 solid solution with 0 ¡Ü x ¡Ü 1.0 by a mechanochemical process without any additional heating. The obtained fine powder was suitable for screen-printing. Particulate precursors were deposited in a thin layer by a screen-printing technique and then the porous precursor layer was sintered into a dense polycrystalline film by atmospheric-pressure firing. The crystal structures of the powder and the film were analyzed by x-ray diffraction and the microstructure of the film was observed in an SEM. For the (Cu1-XAgx)InSe2 films with x ¡Ü 0.2, the (Cu,Ag)InSe2 films had a good microstructure for the solar cell absorbers.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

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