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Establishment of Reaction Phase Diagrams of Pseudo Quaternary Li-Ni-Co-Ti Oxides Library

Published online by Cambridge University Press:  01 February 2011

Kenjiro Fujimoto ,
Kazuhiro Onoda  and
Shigeru Ito
Kenjiro Fujimoto
Affiliation:
fujimoto@rs.noda.tus.ac.jp, Tokyo University of Science, Department of Pure and Applied Chemistry, 2641 Yamazaki, Noda, 278-8510, Japan, +81-4-7124-1501, +81-4-7123-9890
Kazuhiro Onoda
Affiliation:
j7202030@yahoo.co.jp, Tokyo University of Science, Department of Pure and Applied Chemistry, 2641 Yamazaki, Noda, 278-8510, Japan
Shigeru Ito
Affiliation:
ito@rs.noda.tus.ac.jp, Tokyo University of Science, Department of Pure and Applied Chemistry, 2641 Yamazaki, Noda, 278-8510, Japan
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Abstract

Reaction phase diagram of pseudo four-components Li-Ni-Co-Ti oxides was established for finding new chemical composition and functional materials by the combinatorial high-throughput preparation system “M-ist Combi,” based on electrostatic spray deposition process and the combinatorial x-ray powder diffraction apparatus. The new layered-type compounds were found wider composition region than the previous reported composition region of LiNi0.8-yCo0.2TiyO2 (0≤y≤0.1). Furthermore, the new composition regions of single phase for spinel-type and rock salt-type compounds in pseudo four-components Li-Ni-Co-Ti oxides system were also found in a short time.

Keywords

combinatorial synthesispowder processingx-ray diffraction (XRD)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1024: Symposium A – Combinatorial Methods for High-Throughput Materials Science , 2007 , 1024-A01-03
Copyright
Copyright © Materials Research Society 2008

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