Hostname: page-component-8448b6f56d-mp689 Total loading time: 0 Render date: 2024-04-19T11:33:02.569Z Has data issue: false hasContentIssue false

Enabling Thermal Processing of High and Low Dielectric Constant Materials

Published online by Cambridge University Press:  10 February 2011

R. P. S. Thakur
Affiliation:
Micron Process R&D, 8000 S. Federal Way, MS 306 Micron Technology, Inc., Boise, ID 83707, rthakur@micron.com
S. J. DeBoer
Affiliation:
Micron Process R&D, 8000 S. Federal Way, MS 306 Micron Technology, Inc., Boise, ID 83707, rthakur@micron.com
R. Singh
Affiliation:
Department of Electrical and Computer Engineering, 105 Riggs Hall, Clemson University, Clemson, SC 29634
Get access

Abstract

The focus of ULSI electronics is shifting rapidly towards the development and integration of various low and high dielectric constant materials. Memory manufacturers are driving the quest for integration-friendly, high dielectric constant materials, while the logic makers are seeking materials with the lowest possible dielectric constant to use as interlayer dielectrics for their multilayer backend needs. Both of these categories of materials need the highest possible level of reliability, integrability, and manufacturability in the current and upcoming real world. Strong development emphasis in improving the structural aspects of these materials is needed more now than ever before both in university laboratories and industrial R&D. An intense focus on these materials demands immediate, improved, and innovative process solutions. One key process area is the thermal engineering and processing of these materials and hence is the focus of this paper.

In this paper, we present recent results from both university and industry process development work. We compare and contrast the thermal process requirements of some enabling materials with dielectric constants ranging from 2 to more than 100. The examples in our study encompass materials such as Teflon™, PLZT, cell nitride, and tantalum pentoxide. The enhancements in the structural and electrical performance of these materials as a function of thermal cycles used either for deposition or annealing is demonstrated through various examples.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Sze, S. M.. Physics of Semiconductor Devices. 2nd ed., 1981.Google Scholar
2. Thakur, R. P. S., DeBoer, S., Ping, E., and Jesse, C., IEEE Transactions on Electron Devices (to be published).Google Scholar
3. Thakur, R. P. S., Semiconductor Fabtech, 5th ed., p. 261 (1996).Google Scholar
4. Thakur, R. P. S., Weimer, R. A.. DeBoer, S., Schuegraf, K., Powell, C., and Breiner, L., p. 421, RTP 96.Google Scholar
5. Thakur, R. P. S., DeBoer, S. J., Al-Shareef, H. N., Gealy, D., Schuegraf, K., Singh, R., McKinley, K., and Sandier, N., ECS, Spring 1997 (to be published).Google Scholar
6. McKinley, K. and Sandier, N., MRS Fall 1996.Google Scholar
7. Hendricks, N., ECS Spring 1996, p. 196.Google Scholar
8. Singh, R., Sinha, S., Thakur, R. P. S., and Chou, P., Appl. phys. Lett., 58, p. 1217 (1991).Google Scholar
9. Singh, R. and Thakur, R. P. S., The Interface. 4 (3), p. 38 (1995).Google Scholar
10. Singh, R., Sharangpani, R., Cherukuri, K. C., Chen, Y., Dawson, D. M., Poole, K. F., Rohatgi, A., Narayanan, S., and Thakur, R. P. S., Mat. Res. Soc. Symp. Proc., 429 (81) (1996).Google Scholar
11. Singh, R., Cherukuri, K., Vedula, L., Rohatgi, A., and Narayanan, S., Appl. Phys. Lett., 70, 31 March 1997 (in press).Google Scholar
12. Singh, R., Sharangpani, R., and Chen, Y., Advanced Materials CVD (in review).Google Scholar
13. Singh, R., Gong, G., and Chaudhry, J., Proc. TMS/ASM Symposium on Novel Techniques in Synthesis and Processing of Advanced Materials, p. 211, 1994.Google Scholar
14. Sharangpani, R., Singh, R., Drews, M., and Ivey, K., J. Elect. Mat., 26, p. 403 (1997).Google Scholar
15. Chen, Y., Singh, R., DeBoer, S., and Thakur, R. P. S., proc. this conference.Google Scholar
16. Singh, R., Alamgir, S., and Sharangpani, R., Appl. phys. Lett., 67, p. 3939 (1995).Google Scholar
17. Ando, K., Ishitani, A., and Hamano, K., Appl. phys. Lett., 59, p. 1081 (1991).Google Scholar
18. Thakur, R. P. S. and Mathews, V., U.S. Patent 5445999 (29 August 1995).Google Scholar
19. DeBoer, S. J. and Thakur, R. P. S., MRS Spring 1996, p. 225.Google Scholar