Hostname: page-component-7479d7b7d-m9pkr Total loading time: 0 Render date: 2024-07-11T07:32:25.173Z Has data issue: false hasContentIssue false
  • English
  • Français

Electron Microscopical Observations of Graphite in Cast Irons

Published online by Cambridge University Press:  21 February 2011

Gary R. Purdy  and
Marc Audier
Gary R. Purdy
Affiliation:
Dept. of Metallurgy & Materials Science, McMaster University, Hamilton, Ont., Canada L8S 4L7
Marc Audier
Affiliation:
Laboratoire de Thermodynamique et Physico-Chemie Metallurgiques, E.N.S.E.E.G., B.P. 75, 38402 St. Martin d'Heres, France.
Get access

Abstract

Graphite flakes and spheroids, extracted from rare-earth treated cast irons, have been examined using electron microscopy. Transmission microscopy has been used to investigate the defect structure of flakes and to demonstrate the concentric aromatic shell structure of spheroids. Each spheroid is shown to possess a rare-earth containing core or nucleus.

High resolution lattice images are presented as evidence for the presence of amorphous regions within flake graphite crystals. For spheroidal graphite, the lattice images indicate a greater degree of crystalline perfection. In addition, they suggest:

1) The presence of intercalation structures

2) The presence of an amorphous phase, on the graphite-iron interface, from which crystalline graphite forms at growth sites.

The implications for possible mechanisms of graphite crystallization are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 34: Symposium – Physical Metallurgy of Cast Iron , 1984 , 13
Copyright
Copyright © Materials Research Society 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Double, D. and Hellawell, A., Acta Metall. 17, 1071 (1969).10.1016/0001-6160(69)90052-2CrossRefGoogle Scholar
2. Hunter, M.J. and Chadwick, G.A., J. Iron Steel Inst., 210, 117 (1972).Google Scholar
3. Evans, E.L. and Thomas, J.M., J. Solid State Chem. 144, 99–111 (1975).10.1016/0022-4596(75)90366-7Google Scholar
4. Minkoff, I.,“The Physical Metallurgy of Cast Iron”, Wiley-Interscience (1983).Google Scholar
5. Dhindaw, B. and Verhoeven, J.D., Met. Trans. A. 114, 1049–1057 (1980).10.1007/BF02654719Google Scholar
6. Subramanian, S.V., Kay, D.A.R. and Purdy, G.R., AFS Transactions, 589 (1982).Google Scholar
7. Weterfall, S.E., Fredriksson, H., and Hillert, M., J. Iron Steel Inst. 210, 323 (1972).Google Scholar