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Electrodeposited CuInSe2 Thin Film Junctions

Published online by Cambridge University Press:  10 February 2011

R. P. Raffaelle ,
J. G. Mantovani ,
S. G. Bailey ,
A. F. Hepp ,
E. M. Gordon  and
R. Haraway
R. P. Raffaelle
Affiliation:
Florida Institute of Technology, Melbourne, FL 32901, rpr@pss.fit.edu
J. G. Mantovani
Affiliation:
Florida Institute of Technology, Melbourne, FL 32901, rpr@pss.fit.edu
S. G. Bailey
Affiliation:
NASA Lewis Research Center, Cleveland, OH 44135
A. F. Hepp
Affiliation:
NASA Lewis Research Center, Cleveland, OH 44135
E. M. Gordon
Affiliation:
Wilberforce University, Wilberforce, OH 45384
R. Haraway
Affiliation:
Wilberforce University, Wilberforce, OH 45384
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Abstract

We have investigated thin films and junctions based on copper indium diselenide (CIS) which have been grown by electrochemical deposition. CIS is a leading candidate for use in polycrystalline thin film photovoltaic solar cells. Electrodeposition is a cost-effective method for producing thin-film CIS. We have produced both p and n type CIS thin films from the same aqueous solution by simply varying the deposition potential. A CIS pn junction was deposited using a step-function potential. Stoichiometry of the single layer films was determined by energy dispersive spectroscopy. Carrier densities of these films increased with deviation from stoichiometry, as determined by the capacitance versus voltage dependence of Schottky contacts. Optical bandgaps for the single layer films as determined by transmission spectrocopy were also found to increase with deviation from stoichiometry. Rectifying current versus voltage characteristics were demonstrated for the Schottky barriers and for the pn junction.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 495: Symposium W – Chemical Aspects of Electronic Ceramics Processing , 1997 , 383
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1. Rockett, A. and Birkmire, R.W., J. Appl. Phys. 70, R81(1991).Google Scholar
2. Zweibel, K., Ullal, H., and von Roedern, B., 25th IEEE PVSC (IEEE, New York, 1996).Google Scholar
3. Pern, F.J., Goral, J., Maison, R.J., Gessert, T.A., and Noufi, R., Solar Cells 24, 81 (1988)Google Scholar
4. Grindle, S.P., Clark, A.H., Rezaie-Serej, S., Falconer, E., Mcneily, J., and Kazmerski, L.L., J. Appl. Phys. 51, 5464 (1980).Google Scholar
5. Copper Indium Diselenide for Photovoltaic Applications, edited by Couts, T.J., Kazmerski, L.L., and Wagner, S. (Elsevier, Amsterdam, 1986).Google Scholar
6. Zhang, S.B., Wei, S.H., Zunger, A., Phys. Rev. Lett. 78, 21 (1997).Google Scholar
7. Raffaelle, R.P., Mantovani, J.G., and Friedfeld, R.B., Sol. Ener. Mat. & Sol. Cells 46, 201 (1997).Google Scholar
8. Raffaelle, R.P., Mantovani, J.G., Friedfeld, R.B., Bailey, S.G., and Hubbard, S.M., 26th IEEE Photovolt. Spec. Conf. (IEEE, New York, 1997).Google Scholar
9. Johnson, E.J., Semicond. and Semimet. 3, 153 (1967).Google Scholar
10. Irie, T., Endo, S., and Kimura, S., Jpn. J. Appl. Phys. 18, 1303 (1979).Google Scholar
11. Burstein, E., Phys. Rev. 93, 632 (1954);Google Scholar
Moss, S., Proc. Phys. Soc. B 67, 775 (1954).Google Scholar
12. Rincon, C. and Sanchez Perez, G., Solar Cells 16, 363 (1986).Google Scholar
13. Sze, S.M., Physics of Semiconductor Devices (John Wiley & Sons, Inc., New York, 1981).Google Scholar
14. Moller, H.M., Semiconductors for Solar Cells (Artech House, Boston, 1993).Google Scholar
15. Chang, C.Y. and Sze, S.M., Solid State Electron., 13, 727 (1970).Google Scholar
16. Lashmore, D.S. and Dariel, M.P., J. Electrochem. Soc. 135, 1218 (1988).Google Scholar
17. Weast, R.C., ed., CRC Handbook of Chem. and Phys. (CRC, Boca Raton, FL, 1980).Google Scholar