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Electrochemical Self-Assembled of Copper/Copper Oxide Nanowires

Published online by Cambridge University Press:  21 March 2011

S. Kenane
Affiliation:
Unité de Physico-Chimie et de Physique des Matériaux, Place Croix du Sud 1, B-1348 Louvain-la-Neuve, Belgium
L. Piraux
Affiliation:
Unité de Physico-Chimie et de Physique des Matériaux, Place Croix du Sud 1, B-1348 Louvain-la-Neuve, Belgium
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Abstract

Arrays of Cu/Cu 2 O nanowires are electrodeposited at room temperature from alkaline solutions of copper lactate in the nanopores of track-etched polymer membranes. Using the appropriate solution, the electrode potential spontaneously oscillates during the application of a constant cathodic current. Both the period of the oscillations and the composition of the nanowires can be controlled by varying the applied current density. A nanocomposite of copper and cuprous oxide is deposited at an applied current over which oscillations occur. In contrast, pure Cu or Cu 2O nanowires are obtained at deposition current out of the range of oscillation.

Type
Research Article
Copyright
Copyright © Materials Research Society 2002

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References

REFERENCES

1. Whitney, T. M., Jiang, J. S., Searson, P. and Chien, C., Science 261, 1316 (1993).Google Scholar
2. Fert, A. and Piraux, L., J. Mag. Mag. Mater. 200, 338 (1999).Google Scholar
3. Dubois, S., Michel, A., Eymery, J., Duvail, J.L. and Piraux, L., J. Mater. Res. 14, 665 (1999).Google Scholar
4. Martin, C.R., Science 266, 1961 (1994).Google Scholar
5. Huang, Ling-Yuang, Bohannan, Eric W., Hung, Chen-Jen, and Switzer, Jay A., Israel Journal of Chemistry 37, 297301 (1997).Google Scholar
6. Switzer, Jay A., Hung, Chen-Jen, Huang, Ling-Yuang, Miller, F. Scott, Zhou, Yanchun, Raub, Eric R., Shumsky, Mark G., and Bohannan, Eric W., J. Mater. Res. 13 (4), 909916 (1998).Google Scholar
7. Switzer, Jay. A., Hung, Chen-Jen, Huang, Ling-Yuang, Switzer, Eric R., Kammler, Daniel R., Golden, Teresa D., and Bohannan, Eric W., J. Am. Chem. Soc. 120, 35303531 (1998).Google Scholar
8. Bohannan, Eric. W., Huang, Ling-Yuang, Miller, F. Scott, Shumsky, Mark G., and Switzer, Jay. A., Langmuir 15, 813818 (1999).Google Scholar
9. Ferain, E. and Legras, R., Nucl. Instrum. Methods Phys. Res. B174, 116 (2001).Google Scholar
10. Kenane, S. and Piraux, L., Journal of materials research (in press).Google Scholar
11. Dewald, H. D., Parmananda, P. and Rollins, R. W., J. Electrochem. Soc. 140, 1969 (1993).Google Scholar