Skip to main content Accessibility help
×
Home

Effect of the Heat Treatment on the Lithium Insertion Process in MoO3

  • B. Yebka (a1) and C. Julien (a1)

Abstract

We have studied the electrochemical characteristics of Li/MoO3-based batteries in relation with the morphology of the cathode-active material. The oxides and oxide-hydrates of molybdenum have been prepared with various degrees of heat treatement. The samples were characterized by X-ray diffraction, Raman spectroscopy, and conductivity measurements. The effect of the heat treatment on structural, optical and electrochemical properties are presented in this work. Thermodynamics and kinetics of lithium insertion were studied in MoO3 cathodes. Diffusion coefficients and enhancement factors were calculated as functions of the degree of lithium intercalation in the domain of the galvanic cell reversibility.

Copyright

References

Hide All
[1] Julien, C., El-Farh, L., Balkanski, M., Hussain, O.M. and Nazri, G.A., Appl. Surf. Sci. 65-66, 325 (1993).
[2] Hinokuma, K., Kishimoto, A. and Kudo, T., J. Electrochem. Soc. 141, 876 (1994).
[3] Kihlborg, L., Arkiv. Kemi 21, 357 (1963).
[4] Crouch-Baker, S. and Dickens, P.G., Solid State Ionics 32-33, 219 (1989).
[5] Dampier, F.W., J. Electrochem. Soc. 121, 656 (1974).
[6] Margalit, N., J. Electrochem. Soc. 121, 1460 (1974).
[7] Besenhard, J.O. and Schollhorn, R., J. Power Sources 1, 267 (1976/1977).
[8] Christian, P.A., Carides, J.N., DiSalvo, F.J. and Waszczak, J.V., J. Electrochem. Soc. 127, 2315 (1980).
[9] Besenhard, J.O., Heydecke, J., Wudy, E., Fritz, H.P. and Foag, W., Solid State Ionics 8, 61 (1983).
[10] Kumagal, N., Kumagai, N. and Tanno, K., Electrochim. Acta 32, 1521 (1987).
[11] Kumagai, N., Kumagai, N. and Tanno, K., J. Appl. Electrochem. 18, 857 (1988).
[12] Sugawara, M., Kitada, Y. and Matsuki, K., J. Power Sources 26, 373 (1989).
[13] Julien, C. and Nazri, G.A., Solid State Ionics 68, 111 (1994).
[14] Julien, C., Khelfa, A., Guesdon, J.P. and Gorenstein, A., Appl. Phys. A 78, 173 (1994).
[15] Weppner, W. and Huggins, R.A., J. Electrochem. Soc. 124, 1569 (1977).
[16] Gtlnter, J.R., J. Solid State Chem. 5, 354 (1972).
[17] Nazri, G.A. and Julien, C., Solid State Ionics 53-56, 376 (1992).
[18] Anwar, M. and Hogarth, C.A., Int. J. Electronics 66, 901 (1989).
[19] Oswald, H.R., Gunter, J.R. and Dubler, E., J. Solid State Chem. 13, 330 (1975).
[20] Basu, S. and Worrell, W.L., in Fast Ion Transport in Solids, edited by Vashishta, P., Mundy, J.N. and Shenoy, G.K. (North-Holland, Amsterdam, 1979), p. 149.
[21] McKinnon, W.R. and Hearing, R.R., in Modem Aspects of Electrochemistry, vol. 15, edited by White, R., Bockris, J.O'M. and Conway, B.E. (Plenum, New York, 1983), p. 235.

Effect of the Heat Treatment on the Lithium Insertion Process in MoO3

  • B. Yebka (a1) and C. Julien (a1)

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed