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Effect of Processing Parameters on Second Order Nonlinearities of Azo Dye Grafted Hybrid Sol-Gel Coatings

Published online by Cambridge University Press:  10 February 2011

B. Lebeau ,
C. Sanchez ,
S. Brasselet  and
J. Zyss
B. Lebeau
Affiliation:
Laboratoire de Chimie de la Matière Condensée, URA CNRS 1466, Université Pierre et Marie Curie, Paris, FRANCE.
C. Sanchez
Affiliation:
Laboratoire de Chimie de la Matière Condensée, URA CNRS 1466, Université Pierre et Marie Curie, Paris, FRANCE.
S. Brasselet
Affiliation:
Centre National d'Etudes des Télécommunications, France TELECOM, 196 Avenue Henri Ravera, BP 107, 92 225 Bagneux cedex, FRANCE.
J. Zyss
Affiliation:
Centre National d'Etudes des Télécommunications, France TELECOM, 196 Avenue Henri Ravera, BP 107, 92 225 Bagneux cedex, FRANCE.
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Abstract

The synthesis of transparent hybrid organic-inorganic coatings obtained from condensation between 3-isocyanatopropyltriethoxysilane containing grafted azo dyes (ICTES-Red 17) and tetramethoxysilane (TMOS) precursors has been performed. Influence of ICTES-Red 17/TMOS molar composition and thermal curing on both structure and nonlinear optical (NLO) properties of these materials have been investigated. A thermal treatment of ICTES-Red 17/TMOS coatings before poling has been found to improve nonlinear optical responses as well as its stability.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 395
Copyright
Copyright © Materials Research Society 1996

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