Hostname: page-component-84b7d79bbc-c654p Total loading time: 0 Render date: 2024-07-27T21:30:28.975Z Has data issue: false hasContentIssue false

The Effect of Fiber Coatings on Interfacial Shear Strength and the Mechanical Behavior of Ceramic Composites

Published online by Cambridge University Press:  21 February 2011

Richard A. Lowden
Affiliation:
Oak Ridge National Laboratory, P. O. Box 2008, Oak Ridge, TN 37831-6063
Karren L. More
Affiliation:
Oak Ridge National Laboratory, P. O. Box 2008, Oak Ridge, TN 37831-6063
Get access

Abstract

Thin coatings deposited on ceramic fibers prior to densification employing chemical vapor infiltration techniques have been used to limit fiber-matrix bonding. This has resulted in improvements in strength and toughness at room and elevated temperatures in Nicalon® fiber-reinforced/SiC matrix composites. The properties of the fiber-matrix interface in fiber-reinforced ceramic composites have been examined utilizing an indentation method in which a standard microhardness indentor is used to push on fibers embedded in the ceramic matrix. Compositions and microstructures at the interface have been characterized employing analytical electton microscopy. Correlations between interfacial phenomena and observed mechanical behavior have been made.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Rawlins, M. H., Nolan, T. A., Stinton, D. P., and Lowden, R. A., “Interfacial Characterization of Fiber-Reinforced SiC Composites Exhibiting Brittle and Toughened Fracture Behavior,” MRS Symposium Proceedings, Vol. 78, Advanced Structural Ceramics (November 1986).Google Scholar
2. Lowden, R. A., “Characterization and Control of the Fiber-Matrix in Fiber-Reinforced Ceramic Composites,” ORNL/TM-11039, March 1989.Google Scholar
3. Brennan, J. J., “Interfacial Chemistry and Bonding in Fiber Reinforced Glass and GlasscCeramic Composites,” Ceramic Microstructures '86: Role of Interfaces, University of California, Berkeley (July 1986).Google Scholar
4. Brennan, J. J., “Interfacial Characteristics of Glass-Ceramic Matrix/SiC Fiber Composites,” Interface Science and Engineering '87, Lake Placid, New York (July 1987).Google Scholar
5. Brennan, J. J., “Interfacial Characteristics of Glass and Glass-Ceramic Matrix/Nicalon SiC Fiber Composites,” Proceedings of “Tailoring Multiphase and Composite Ceramics,” Ed. by Tressler, R. E., etal., Penn. St. Univ., 549–560 (July 1985).Google Scholar
6. Kotlensky, W. V., “Deposition of Pyrolytic Carbon in Porous Solids,” Chem. Phys. Carbon 9, 173262 (1973).Google Scholar
7. Pierson, H. O. and Lieberman, M. L., “The Chemical Vapor Deposition of Carbon on Carbon Fibers,” Carbon 13, 159–66 (1975).Google Scholar
8. Stinton, D. P., Caputo, A. J. and Lowden, R. A., “Synthesis of Fiber-Reinforced SiC Composites by Chemical Vapor Infiltration,” Am. Ceram. Soc. Bull. 65(2), 347–50 (1986).Google Scholar
9. Rice, R. W., et al., “The Effect of Ceramic Fiber Coatings on the Room-Temperature Behavior of Ceramic-Fiber Composites,” Ceram. Eng. Sci. Proc. 2(7–8),661701 (1981).Google Scholar
10. Bender, B., et al., “Effect of Fiber Coatings and Composite Processing of Properties of Zirconia-Based Matrix SiC Fiber Composites,” Am. Ceram. Soc. Bull. 65(2), 363–9 (1986).Google Scholar
11. Caputo, A. J., Stinton, D. P., Lowden, R. A., and Besmann, T. M., “Fiber-Reinforced SiC Composites with Improved Mechanical Properties,” Am. Ceram. Soc. Bull. 66(2), 268–72 (1987).Google Scholar
12. Marshall, D. B., “An Indentation Method for Measuring Matrix-Fiber Frictional Stresses in Ceramic Components,” Comm. Amer. Ceram. Soc. C259–60 (December 1984).Google Scholar
13. Caputo, A. J., Lowden, R. A., and Stinton, D. P., Improvements in the Fabrication of Ceramic-Fiber-Ceramic-Matrix Composites by Chemical Vapor Deposition, ORNL/TM-9652, June 1985.Google Scholar
14. Stinton, D. P., Caputo, A. J., and Lowden, R. A., “Synthesis of Fiber-Reinforced SiC Composites by Chemical Vapor Infiltration,” Am. Ceram. Soc. Bull. 65(2), 347–50 (1986).Google Scholar
15. Lowden, R. A., Caputo, A. J., Stinton, D. P., Besmann, T. M., and Morris, M. K., Effects of Infiltration Conditions on the Properties of SiC/Nicalon Composites, ORNL/TM-10403, May 1987.Google Scholar
16. Mandell, J. F., “Modified Microdebonding Test for Direct In Situ Fiber/Matrix Bond Strength Determination in Fiber Composites,” Composite Materials: Testing and Design (Seventh Conference), ASTM STP 893, Whitney, J. M., Ed., American Society for Testing and Materials, Philadelphia, 1986, pp. 87–108.Google Scholar
17. Marshal, D. B. and Oliver, W. C., “Measurement of Interfacial Mechanical Properties in Flber-Reinforced Ceramic Composites,” J. Am. Ceram. Soc. 70(8), 542–8 (1987).Google Scholar