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The Diffusion of Chloride Ions in Fly Ash/Cement Pastes and Mortars

Published online by Cambridge University Press:  25 February 2011

R. I. A. Malek
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
D. M. Roy
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802 Also affiliated with the Department of Materials Science and Engineering
P. H. Licastro
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
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Abstract

Fly ashes having three distinctly different levels of calcium, designated low-calcium (Class F), intermediate-calcium (Class F/C), and high-calcium (Class C) comprised the basic material for the present study. Pastes and mortars were made out of the three types of fly ashes and one type of cement (Type I) at various levels of replacement as well as different water/solid ratios (w/c). Chloride ion diffusion was measured by applying an electrical potential across cured cylindrical samples and measuring the amount of current passed in a certain period of time (proportional to amount of Cl passed in this time). Other supportive measurements were made, e.g., porosity and pore size distribution, water permeability and surface area. The Cl ion diffusivities were correlated with the chemical composition of fly ash (FA), mix proportioning, and water permeabilities of the tested hardened pastes or mortars.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

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References

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