Hostname: page-component-8448b6f56d-c4f8m Total loading time: 0 Render date: 2024-04-25T02:29:40.495Z Has data issue: false hasContentIssue false

Dielectric Properties of Piezoelectric Polyimides

Published online by Cambridge University Press:  10 February 2011

Z. Ounaies
Affiliation:
National Research Council, NASA Langley Research Center, Hampton, VA 23681
J. A. Young
Affiliation:
University of Virginia, Department of Materials Science and Engineering, Charlottesville, VA 22903
J. O. Simpson
Affiliation:
Composites and Polymers Branch, NASA Langley Research Center, Hampton, VA 23681
B. L. Farmer
Affiliation:
University of Virginia, Department of Materials Science and Engineering, Charlottesville, VA 22903
Get access

Abstract

Molecular modeling and dielectric measurements are being used to identify mechanisms governing piezoelectric behavior in polyimides such as dipole orientation during poling, as well as degree of piezoelectricity achievable. Molecular modeling on polyimides containing pendant, polar nitrile (CN) groups has been completed to determine their remanent polarization. Experimental investigation of their dielectric properties evaluated as a function of temperature and frequency has substantiated numerical predictions. With this information in hand, we are then able to suggest changes in the molecular structures, which will then improve upon the piezoelectric response.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Simpson, J. O.. Welch, S. S. and Clair, T. L. St., in Electrical, Optical and Magnetic Properties of Organic Solid State Materials III. edited by Jen, A. K-Y., Lee, C. Y-C., Dalton, L. R., Rubner, M. F. and Wnek, G. E. (Mater. Res. Soc. Proc. 143, Boston, MA 1995), p. 351356.Google Scholar
2. Hinkley, J. A., High Performance Polymers 8, (1996).Google Scholar
3. Furukawa, T., IEEE Trans. Elec. Ins. 24, 375 (1989).Google Scholar
4. Young, J. A., (to be published).Google Scholar
5. Hilezer, B. and Mlecki, J., Electrets. Polish Scientific Publishers, Warszawa, 1986.Google Scholar
6. Ibar, J. P., Denning, P., Thomas, T., Bernes, A., de Goys, C., Saffell, J. R., Jones, P. and Lacabanne, C., in Polymer Characterization: Physical Property. Spectroscopy.and Chromotographic methods, edited by Craver, C. D. and Provder, T. (Adv. Chem. Series 227, 1990), p. 167190.Google Scholar
7. Tasaka, S., Toyama, T. and Inagaki, N., Jpn. J. Appl. Phys. 33, 5838 (1994).Google Scholar
8. Tasaka, S., Inagaki, N., Okutani, T. and Miyata, S., Polymer 30, 1639 (1989).Google Scholar