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Design of a Passive-Matrix Smart Window by the Conjugated Polymer Electrochromics

  • Rei Furukawa (a1), Chunye Xu (a2) and Minoru Taya (a3)

Abstract

Preliminary development towards passive matrix Electrochromic (EC) device in conjugated EC polymer system is discussed. High contrast ratio of dark and bleached pixels is obtained by modification of counter and working electrode capacitance ratio and spacer geometry. Mask patterning and laminar electropolymerization for multicolor EC system application is discussed.

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1 Argun, A. A., Aubert, P.-H., Thompson, B. C., Schwendeman, I., Gaupp, C. L., Hwang, J., Pinto, N. J., Tanner, D. B., MacDiarmid, A. G., Reynolds, J. R., “Multicolored electrochromisin in polymers: Structures and devices”, Chemistry of Materials v 16, n 23, Nov 16, p 44014412, 2004
2 Welsh, D. M., Kumar, A, Meijer, E. W., Reynolds, J. R., “Enhanced Contrast Ratios and Rapid Switching in Electrochromics Based on Poly (3,4-propylenedioxythiophene) Derivatives”, Adv. Mater. 11, No 16, 1999
3 Chandrasekhar, P., Zay, B. J., Birur, G. C., Rawal, S., Pierson, E. A., Kauder, L., Swanson, T., “Large, switchable electrochromism in the visible through far-infrared in conducting polymer devices”, Advanced Functional Materials, v 12, n 2, p 95103, February, 2002
4 Xu, C., Tamagawa, H., Uchida, M., Taya, M., “Enhanced Contrast Ratios and Rapid Switching Color Changeable Devices Based on Poly(3,4-propylenedioxythiophene) Derivative and Counterelectrode”, Proceedings of SPIE - The International Society for Optical Engineering, v 4695, p 442450, 2002
5 Edwards, M.O.M., “Passive-matrix addressing of viologen-TiO2 displays”, Applied Physics Letters, v 86, 2005
6 Takahashi, K., Limmer, S. J., Wang, Y., Cao, G.. “Synthesis and electrochemical properties of single-crystal V2O5 nanorod arrays by template-based electrodeposition”, Journal of Physical Chemistry B, 108:9795, 2004

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Design of a Passive-Matrix Smart Window by the Conjugated Polymer Electrochromics

  • Rei Furukawa (a1), Chunye Xu (a2) and Minoru Taya (a3)

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