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A Defect Equilibrium Treatment of Selected Transport Phenomena in Solids

Published online by Cambridge University Press:  28 February 2011

Steven Crouch-Baker*
Affiliation:
Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, CA 90024, U.S.A.
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Abstract

Some aspects of the thermodynamic and transport - related properties of binary solid electrolyte phases are discussed in terms of the associated defect behaviour. In particular, the close relationship between results obtained from an asymmetric polarization experiment and the relevant defect equilibrium diagram for the phase under study, is emphasized.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

1. Kroger, F. A., The ChemistEy of Imperfect Crystals, 2nd ed. (North - Holland, Amsterdam, 1974).Google Scholar
2. Brouwer, G., Phillips Res. Rep. 2, 366 (1954).Google Scholar
3. Krdger, F. A., Vink, H. J. and Boomgard, J. van den, Z. Phys. Chem. 203, 1 (1954).Google Scholar
4. Wagner, C., Z. Elektrochem. 60, 4 (1956).Google Scholar
5. Hebb, M., J. Chem. Phys. 20, 185 (1958).CrossRefGoogle Scholar
6. Rickert, H., Electrochemistry of Solids (Springer - Verlag, Berlin, 1982).Google Scholar
7. Heyne, L., in Topics in Applied Physics - Solid Electrolytes, edited by Geller, S. (Springer - Verlag, 1977), p. 169.CrossRefGoogle Scholar
8. Wagner, C., in Advances in Electrochemistry and Electrochemical Engineering, vol. 4, edited by Delahay, P. (Interscience, New York, 1966), p. 1.Google Scholar