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Crystal Structure Change with Applied Electric Field for (100)/(001)-oriented Polycrystalline Lead Zirconate Titanate Films

  • Ayumi Wada (a1) (a2), Yoshitaka Ehara (a1), Shintaro Yasui (a1), Takahiro Oikawa (a1), Mitsumasa Nakajima (a1), Megu Wada (a1), P. S. Sankara Rama Krishnan (a1), Soichiro Okamura (a2), Ken Nishida (a3), Takashi Yamamoto (a3), Takeshi Kobayashi (a4), Hitoshi Morioka (a5) and Hiroshi Funakubo (a1)...

Abstract

Crystal structure change with an applied electric field was investigated by Raman spectroscopy and X-ray diffraction (XRD) for the 1 μm-thick (100)/(001) one-axis oriented tetragonal Pb(Zr0.3Ti0.7)O3 films prepared on Pt-covered (100) Si substrates by chemical solution deposition technique. As-deposited films were under the strained condition in good agreement with the estimation from the thermal strain applied under the cooling process after the deposition from the Curie temperature to the room temperature. This strain was ascertained to be relaxed by an applied electric field in accompanying with the dramatic increase of the volume fraction of (001) orientation. These results demonstrate the importance of the crystal structure measurement not only as-deposited films, but also after applied electric field, such as after poling.

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Keywords

Crystal Structure Change with Applied Electric Field for (100)/(001)-oriented Polycrystalline Lead Zirconate Titanate Films

  • Ayumi Wada (a1) (a2), Yoshitaka Ehara (a1), Shintaro Yasui (a1), Takahiro Oikawa (a1), Mitsumasa Nakajima (a1), Megu Wada (a1), P. S. Sankara Rama Krishnan (a1), Soichiro Okamura (a2), Ken Nishida (a3), Takashi Yamamoto (a3), Takeshi Kobayashi (a4), Hitoshi Morioka (a5) and Hiroshi Funakubo (a1)...

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