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Composite nanosilver structures suitable for plasmonic biosensors

Published online by Cambridge University Press:  07 March 2012

Georgios A. Sotiriou
Affiliation:
Particle Technology Laboratory, Institute of Process Engineering Department of Mechanical and Process Engineering Swiss Federal Institute of Technology Zurich (ETH Zurich)
Christoph O. Blattmann
Affiliation:
Particle Technology Laboratory, Institute of Process Engineering Department of Mechanical and Process Engineering Swiss Federal Institute of Technology Zurich (ETH Zurich)
Sotiris E. Pratsinis
Affiliation:
Particle Technology Laboratory, Institute of Process Engineering Department of Mechanical and Process Engineering Swiss Federal Institute of Technology Zurich (ETH Zurich)
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Abstract

Silver (Ag) nanoparticles dispersed in an amorphous silica (SiO2) matrix or coated by a SiO2 layer were synthesized by flame spray pyrolysis (FSP). The coated nanoparticles were produced by using a modified enclosed FSP setup, in which the SiO2 precursor was injected through a ring above the FSP nozzle at various burner-ring-distances (BRDs), after the core Ag nanoparticles had been formed. The produced nanoparticles were characterized by XRD, BET, TEM and UV/vis analysis. The Ag particle size was possible to be controlled by tuning the FSP parameters. For the SiO2 coated nanoparticles, larger Ag core sizes were obtained for higher BRDs. All the produced nanoparticles exhibited the characteristic plasmon resonance frequency of Ag nanoparticles.

Type
Research Article
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

1. Sun, Y. G.; Xia, Y. N. Shape-controlled synthesis of gold and silver nanoparticles Science 2002, 298, 21762179.Google Scholar
2. Evanoff, D. D.; Chumanov, G. Synthesis and optical properties of silver nanoparticles and arrays ChemPhysChem 2005, 6, 12211231.Google Scholar
3. LizMarzan, L. M.; Giersig, M.; Mulvaney, P. Synthesis of nanosized gold-silica core-shell particles Langmuir 1996, 12, 43294335.Google Scholar
4. Sotiriou, G. A.; Hirt, A. M.; Lozach, P. Y.; Teleki, A.; Krumeich, F.; Pratsinis, S. E. Hybrid, silica-coated, Janus-like plasmonic-magnetic nanoparticles Chem. Mater. 2011, 23, 19851992.Google Scholar
5. Sotiriou, G. A.; Pratsinis, S. E. Engineering nanosilver as an antibacterial, biosensor and bioimaging material Curr. Opin. Chem. Eng. 2011, 1, 310.Google Scholar
6. Sotiriou, G. A.; Sannomiya, T.; Teleki, A.; Krumeich, F.; Vörös, J.; Pratsinis, S. E. Non-toxic dry-coated nanosilver for plasmonic biosensors Adv. Funct. Mater. 2010, 20, 42504257.Google Scholar
7. Han, Y.; Jiang, J.; Lee, S. S.; Ying, J. Y. Reverse microemulsion-mediated synthesis of silica-coated gold and silver nanoparticles Langmuir 2008, 24, 58425848.Google Scholar
8. Lu, Y.; Yin, Y. D.; Li, Z. Y.; Xia, Y. A. Synthesis and self-assembly of Au@SiO2 core-shell colloids Nano Lett. 2002, 2, 785788.Google Scholar
9. Liu, S. H.; Han, M. Y. Synthesis, functionalization, and bioconjugation of monodisperse, silica-coated gold nanoparticles: Robust bioprobes Adv. Funct. Mater. 2005, 15, 961967.Google Scholar
10. Madler, L.; Kammler, H. K.; Mueller, R.; Pratsinis, S. E. Controlled synthesis of nanostructured particles by flame spray pyrolysis J. Aerosol. Sci. 2002, 33, 369389.Google Scholar
11. Strobel, R.; Pratsinis, S. E. Flame aerosol synthesis of smart nanostructured materials J. Mater. Chem. 2007, 17, 47434756.Google Scholar
12. Teleki, A.; Heine, M. C.; Krumeich, F.; Akhtar, M. K.; Pratsinis, S. E. In-situ coating of flame-made TiO2 particles by nanothin SiO2 films Langmuir 2008, 24, 1255312558.Google Scholar
13. Yaws, C. L.; Narasimhan, P. K.; Gabbula, C. Yaws’ Handbook of Antoine coefficients for vapor pressure (Electronic edition) Knovel 2005,Google Scholar
14. Quinten, M. The color of finely dispersed nanoparticles Appl. Phys. B-Lasers Opt. 2001, 73, 317326.Google Scholar