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The Chemistry and Characteristics of Nitric Acid-Graphite Intercalation

Published online by Cambridge University Press:  15 February 2011

Sophia R. Su  and
Daniel W. Oblas
Sophia R. Su
Affiliation:
GTE Laboratories, Inc., Waltham, Massachusetts, 02254, USA
Daniel W. Oblas
Affiliation:
GTE Laboratories, Inc., Waltham, Massachusetts, 02254, USA
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Abstract

Gas-phase intercalation of graphite by nitric acid is a one-step process. The weight uptake of the sample is a function of nitric acid vapor pressure. A pure second stage compound was formed when the HNO3 reservoir was maintained at 17°C. Only a fourth stage compound was formed when the acid was kept at 0°C. The product gases due to intercalation and gas species evolved during deintercalation were analyzed by mass spectrometry. NO2 and H2O were the major components detected from the intercalation product gases. A small amount of oxygen was also present. The existence of O2 is probably due to the photo-chemical decomposition of nitric acid. As such, the photodecomposition of nitric acid is not a contributory factor in the intercalation chemistry.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 20: Symposium H – Intercalated Graphite , 1982 , 231
Copyright
Copyright © Materials Research Society 1983

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References

REFERENCES

1. Forsman, W.C., Vogel, F.L., Carl, D.E. and Hoffman, J., Carbon 16, 269 (1978).CrossRefGoogle Scholar
2. Loughlin, S., Grayeski, R. and Fischer, J.E., J. Chem. Phys. 8, 3740 (1978).CrossRefGoogle Scholar
3. Forsman, W.C., Carl, D.E. and Vogel, F. L., Mat. Sci. Eng. 47, 187 (1981).CrossRefGoogle Scholar
4. Cotton, F.A. and Wilkinson, G., Advanced Inorganic Chemistry, 4th Edition, (John Wiley and Songs, New York 1980) p. 243.Google Scholar
5. Organic Synthesis Collective, vol. 3, p. 804 (1955).CrossRefGoogle Scholar
6. Ubbelohde, A.R., Proc. Roy. Soc. (London) A304, 25 (1968).Google Scholar
7. Zeller, C., Denenstein, A. and Foley, G.M.T., Rev. Sci. Instrum. 50, 602 (1979).CrossRefGoogle Scholar
8. Nixon, D.E., Parry, G.S. and Ubbelohde, A.R., Proc. R. Soc. (London) A291, 324 (1966).Google Scholar
9. Vogel, F.L., Molecular Metals, edited by Hatfield, W.E. (New York: Plenum Press 1979), pp. 261–279.CrossRefGoogle Scholar