Hostname: page-component-8448b6f56d-sxzjt Total loading time: 0 Render date: 2024-04-19T21:32:06.929Z Has data issue: false hasContentIssue false

Chemical Wear of Cu CMP

Published online by Cambridge University Press:  14 March 2011

Hong Liang*
Affiliation:
University of Alaska Fairbanks; Jean-Michel Martin and Beatrice Vacher, Ecole Centrale de Lyon; and Vlasta Brusic, Cabot Corporation
Get access

Extract

In this work, we used surface analysis techniques, such as a field-emission highresolution analytical TEM, X-ray spectroscopy, and XPS to analyze abrasive particles after polishing. Results showed evidence of copper oxide (Cu2O) in the polished slurry. However, there was no metallic crystalline copper detected. After comparing these data with the results obtained from our electro-chemical experiments, we propose two possible chemical wear mechanisms in Cu CMP.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Larsen-Basse, J. and Liang, H., “Probable Roles of Abrasive Particles in W CMP,” Wear, 233–235, 647654, 1999.10.1016/S0043-1648(99)00248-3Google Scholar
2 Kaufman, F. B., Thompson, D. B., Broadie, R. E., Jaso, M. A., Gutherie, W. L., Pearson, D. J. and Small, M. B., “Chemical-Mechanical Polishing for Fabricating Patterned W Metal Features as Chip Interconnects,” J. Electrochem. Soc., 138, 3460, 1991.10.1149/1.2085434Google Scholar
3 Stein, D., Hetherington, d., Guilinger, T., and Cecchi, J., “In Situ Electrochemical Investigation of Tungsten Electrochemical Behavior during Chemical Mechanical Polishing,” J. Eletrochem. Soc., 145, 3190, 1998.10.1149/1.1838785Google Scholar
4 Martin, J. M., Mogne, Th. Le, Boehm, M., and Grossiord, C., “Tribochemisty in the Analytical UHV Tribometer,” Trib. Int., in press.Google Scholar
5 Martin, J. M., Mogne, Th. Le, Grossiord, C., and Palermo, Th., “Tribochemistry in the Analytical UHV Tribometer,” Trib. Let., 3, 8794, 1997.10.1023/A:1019183711497Google Scholar
6 Martin, J.M., “Antiwear Mechanisms of Zinc Dithiophosphate: a Chemical Hardness Approach,” Tribology Letters, Vo. 6, 18, 1999.10.1023/A:1019191019134Google Scholar
7 Dickinson, J.T., Park, N.-S., Kim, M-W., and Langford, S.C., “A Scanning Force Microscope Study of a Tribochemical System: Stress-Enhanced Dissolution,” Trib. Lett. 3, 6980, 1997.10.1023/A:1019135828336Google Scholar
8 Varlot, K., Martin, J. M., Grossiord, C., Vacher, B., and Inoue, K., “A Dual Analysis Approach in Tribochemistry: Application to ZDDP/calcium Borate Additive Interactions,” Trib. Letters.Google Scholar
9 Brusic, B., Scherber, D., Kaufman, F., Kistler, R., and Streinz, C., “Electrochemical Approach to Au and Cu CMP Process Development,” The Electrochemical Society Proceedings, V. 96-22, 176185, 1997.Google Scholar
10 Brusic, V. and Liang, H., Private Conversation.Google Scholar
11 Brusic, V., Frisch, M. A., Eldridge, B. N., Novak, F. P., Kaufman, F. B., Rush, B. M., and Frankel, G. S., Copper Corrosion with and without Inhibitors,” J. Electrochem. Soc., Vol. 138, No. 8, 22532259, 1991.10.1149/1.2085957Google Scholar