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Cation Distribution in Transition Metal Oxide Spinels: Thermodynamic and Kinetic Considerations

  • S. E. Dorris (a1), D. S. Erickson (a1) and T. O. Mason (a1)

Abstract

The point defect reaction which governs the magnetic and electrical properties of transition metal oxide spinels is the distribution of cations between tetrahedral and octahedral sublattices. Two types of redistribution occur -- ionic and electronic. The thermodynamics and kinetics of these processes can be studied via the electrical properties, thermoelectric coefficient and conductivity.

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Cation Distribution in Transition Metal Oxide Spinels: Thermodynamic and Kinetic Considerations

  • S. E. Dorris (a1), D. S. Erickson (a1) and T. O. Mason (a1)

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