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C60 with Metalloporphyrins

Published online by Cambridge University Press:  25 February 2011

Alain Penicaud ,
John Hsu  and
Christopher Reed
Alain Penicaud
Affiliation:
Department of Chemistry, University of Southern California, Los Angeles, CA 90089–0744
John Hsu
Affiliation:
Department of Chemistry, University of Southern California, Los Angeles, CA 90089–0744
Christopher Reed
Affiliation:
Department of Chemistry, University of Southern California, Los Angeles, CA 90089–0744
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Abstract

CrII(OEP) (OEP: Dianion of octaethylporphyrin) quantitatively reacts with C60 in a THF-toluene (THF: tetrahydrofurane) mixture to give purple-black crystals of formula Cr(OEP)(C60)(THF)x. ESR and SQUID measurements show this compound to be a salt better described as [Cr(OEP)(THF)2+][(C60)−].THF(x-2). ESR spectra in frozen 2-Me-THF show an anisotropie signal centered at g = 1.998.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 307
Copyright
Copyright © Materials Research Society 1992

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References

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