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Bonding and Penetration at Metal/Self-Assembled Organic Monolayer Interfaces

Published online by Cambridge University Press:  15 February 2011

D. R. Jung ,
A. W. Czanderna  and
G. C. Herdt
D. R. Jung
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401
A. W. Czanderna
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401
G. C. Herdt
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401
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Abstract

The purpose of research on metals (M) deposited onto self-assembled monolayers (SAMs) is to understand the interactions between the metal and eventually metal oxide overlayers on well-ordered organic substrates. Applications of M/SAM and inorganic/SAM research results to the understanding of real inorganic/organic interfaces in vacuum and under environmental conditions can potentially play a key role in the development of advanced devices with stable interfacial properties. The results of selected M/SAM studies to date are reviewed, and MISAM combinations ranked according to reactivity and penetration. Specific examples of reactive interfaces (Cu/COOH, Cr/several groups) and nonreactive interfaces with penetration (Ag/CH3, Ag/COOH) are used to illustrate the extremes.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 385: Symposium N – Polymer/Inorganic Interfaces II , 1995 , 11
Copyright
Copyright © Materials Research Society 1995

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References

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