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Band offsets at the ZnSe / CuInS2 interface

Published online by Cambridge University Press:  01 February 2011

S. Siebentritt
Affiliation:
Hahn-Meitner-Institut, Glienicker Str. 100, D-14109 Berlin, Germany
I. Lauermann
Affiliation:
Hahn-Meitner-Institut, Glienicker Str. 100, D-14109 Berlin, Germany
T. Hahn
Affiliation:
Friedrich-Schiller-Universität Jena, Institut für Festkörperphysik, Max-Wien-Platz 1, D-07743 Jena, Germany
H. Metzner
Affiliation:
Friedrich-Schiller-Universität Jena, Institut für Festkörperphysik, Max-Wien-Platz 1, D-07743 Jena, Germany
M. Ch. Lux-Steiner
Affiliation:
Hahn-Meitner-Institut, Glienicker Str. 100, D-14109 Berlin, Germany Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany
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Abstract

ZnSe has been shown to be a promising alternative buffer in CuInS2 thin film solar cells. Here we present for the first time photoemission measurements to determine the band alignment at the ZnSe/CuInS2 interface. Epitaxial CuInS2 is used as a substrate. ZnSe is deposited in varying thicknesses by MOCVD. X-ray photoelectron spectra are measured with an Mg laboratory source and with synchrotron radiation. A valence band offset of 0.4+/-0.1eV is obtained.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

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References

1 Papathanasiou, O., Siebentritt, S., Bohne, W., Klaer, J., Lauermann, I., Rahne, K., Röhrich, J., Rusu, M., Strub, E., Lux-Steiner, M. Ch., Cd-free buffer layers for CuInS2 solar cells prepared by a dry process. 19th EU-PVSEC, 2004: p. 1951.Google Scholar
2 Hashimoto, Y., Takeuchi, K., Ito, K., Band aligment at CdS/CuInS2 heterojunction. Jpn., Appl. Phys. Lett., 1995. 67(7): p. 980.Google Scholar
3 Klenk, R., Characterization and Modelling of Chalcopyrite Solar Cells. Thin Solid Films, 2001. 387: p. 135.Google Scholar
4 Siebentritt, S., Kampschulte, T., Bauknecht, A., Blieske, U., Harneit, W., Fiedeler, U., Lux-Steiner, M. C., Cd-free buffer layers for CIGS solar cells prepared by a dry process. Solar Energy Mat. Solar Cells, 2002. 70: p. 447.Google Scholar
5 Fujita, S., Fujita, S., Photoassisted metalorganic vapor phase epitaxial growth of wide gap II-VI semiconductors. J. Crystal Growth, 1992. 117: p. 67.Google Scholar
6 Gossla, M., Hahn, Th., Metzner, H., Conrad, J., Geyer, U., Thin CuInS2 films by three source molecular beam deposition. Thin Solid Films, 1995. 268: p. 39.Google Scholar
7 Nelson, A., Gebhard, S., Rockett, A., Covalita, E., Engelhardt, M., Höchst, H., Synchrotronradiation photoemission study of CdS/CuInSe2 heterojunction formation. phys. Rev. B, 1990. 42(12): p. 7518.Google Scholar
8 Hunger, R., Pettenkofer, C., Scheer, R., Surface properties of (111), (001) and (110) oriented epitaxial CuInS2/Si films. Surf. Sci., 2001. 477: p. 76.Google Scholar
9 Scheer, R., Luck, I., Lewerenz, H., J. Photoemission Study on CuInS2 Thin Film for Efficient Solar Energie Conversion. in 12th Eu PVSEC. 1994.Google Scholar
10 Weinhart, L., Fuchs, O., Gross, D., Storch, G., Umbach, E., Dhere, N.G., Kadam, A.A., Kulkarni, S. S., Heske, C., Band aligment at the CdS/Cu(In,Ga)S2 interface in thin-film solar cells. Appl. Phys. Lett., 2005. 86(6): p. 62109.Google Scholar