Hostname: page-component-76fb5796d-5g6vh Total loading time: 0 Render date: 2024-04-25T13:46:13.567Z Has data issue: false hasContentIssue false

Adsorption of Oxygen on Sodium Saturated Cu{110}

Published online by Cambridge University Press:  25 February 2011

D. E. Grider
Affiliation:
Honeywell Physical Sciences Center, Bloomington, MN 55420, USA
J. F. Wendelken
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6024, USA
Get access

Abstract

The adsorption of oxygen on a sodium saturated Cu{110} surface is examined with x-ray photoelectron spectroscopy (XPS) in an extension of a previous study of this system which utilized low energy electron diffraction (LEED), and high resolution electron energy loss spectroscopy (HREELS). The sodium overlayer, despite the presence of an initial oxide contaminant, shows metallic character. Intentionally adsorbed oxygen is in a different chemical state than the initial oxygen contaminant and causes a reduction in the metallic character of the sodium. The sticking coefficient for oxygen on the sodium saturated surface is almost three times greater than for the bare Cu{11O} surface.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Grider, D. E. and Wendelken, J. F., Surf. Sci. 185, 431 (1987)CrossRefGoogle Scholar
2. Kitson, M. and Lambert, R. M., Surf. Sci. 109, 60(1981)CrossRefGoogle Scholar
3. Spencer, N. D. and Lambert, R. M., Chem. Phys. Lett. 83, 388 (1981)Google Scholar
4. Garfunkel, E., Ding, X., Dong, G., Yang, S., Huo, X., and Wang, X., Surf. Sci. 164 511 (1985)Google Scholar
5. Prince, K. C. and Kordesch, M. E., Appl. Surf. Sci. 22/23, 469 (1985)Google Scholar
6. Hayden, B. E., Prince, K. C., Daive, P. J., Paolucci, G. and Bradshaw, A. M., Solid State Commun. 48, 325 (1983)Google Scholar
7. Lindgren, S. A. and Wallden, L., Surf. Sci. 89, 319 (1979)Google Scholar
8. Lindgren, S. A. and Wallden, L., Phys. Rev.B 12, 5967 (1980)Google Scholar
9. Kiskanova, M., Rangelov, G. and Surnev, L., Surf. Sci. 150, 339 (1985)CrossRefGoogle Scholar
10. Barrie, A. and Street, F. J., J. Electron Spectrosc. Relat. Phenom. 7, 1 (1975)CrossRefGoogle Scholar
11. Citrin, P. H., Phys. Rev. B 8, 5545 (1973)Google Scholar
12. Fuggle, J. C. and Martensson, N., J. Electron Spectrosc. Relat. Phenom. 21, 275 (1980)Google Scholar
13. Kowalczyk, S. P., Ley, L., McFeely, F. R., Pollak, R. A., and Shirley, D. A., Phys. Rev. B 8, 3583 (1973)Google Scholar
14. Gruzalski, G. R., Zehner, D. M., Wendelken, J. F., and Hathcock, R. S., Surf. Sci. 151, 430 (1985)Google Scholar
15. GruzaTsi, G. R., Zehner, D. M., Wendelken, J. F., Surf. Sci. 159, 151 (1985)Google Scholar