Hostname: page-component-8448b6f56d-dnltx Total loading time: 0 Render date: 2024-04-25T01:49:19.779Z Has data issue: false hasContentIssue false
  • English
  • Français

Adhesive Systems Based on Functionalized Block Copolymers

Published online by Cambridge University Press:  15 February 2011

Randall S. Saunders  and
Michael S. Kent
Randall S. Saunders
Affiliation:
Sandia National Labs, Dept. 1815, Box 5800, Albuquerque, NM. 87185-0367
Michael S. Kent
Affiliation:
Sandia National Labs, Dept. 1815, Box 5800, Albuquerque, NM. 87185-0367
Get access

Abstract

Functionalized block copolymers were synthesized as adhesion promoters using Ring-Opening Metathesis Polymerization (ROMP). They were designed for glass/epoxy and copper/epoxy interfaces. The former contained triethoxysilane groups in the first block and secondary amine groups in the second. The latter contained imidazole groups in the first and amine groups in the second block. These block copolymers were shown to form ordered monolayers on the respective glass and copper surfaces using neutron reflectivity. Adhesion measurements showed an enhancement of adhesion after application of these block copolymers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 385: Symposium N – Polymer/Inorganic Interfaces II , 1995 , 137
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Grubbs, R. H. and Tumas, W., Science, 243, 902 (1989).Google Scholar
2. Schrock, R. R., Acc. Chem. Res., 23, 158 (1990).Google Scholar
3. Schrock, R. R. et al, J. Am. Chem. Soc., 112, 3875 (1990).Google Scholar
4. Schrock, R. R. et al, Macromolecules, 24, 4495 (1991).Google Scholar
5. Schrock, R. R. et al, J. Am. Chem. Soc., 113, 6899 (1991).Google Scholar
6. Saunders, R. S. et al, Macromolecules, 25, 2055 (1992).Google Scholar
7. Saunders, R. S. et al, Macromolecules, 24, 5599 (1991)(and references contained therein).Google Scholar