Skip to main content Accessibility help
×
Home

Second Harmonic Generation from Multilayers of Oriented Metal Bisphosphonates

Published online by Cambridge University Press:  15 February 2011


Grace Ann Neff
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.
Timothy M. Mahon
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.
Travis A. Abshere
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.
Catherine J. Page
Affiliation:
Department of Chemistry, University of Oregon, Eugene, OR 97403.

Abstract

Second order nonlinear optical properties (NLO) require the presence of a polarizable moiety situated in an anharmonic potential. Our approach to incorporating such properties into self-assembled multilayers involves use of asymmetric α,ω bisphosphonates which meet this requirement by virtue of their chemical structure and binding properties. We have developed and optimized protection and deprotection schemes to allow for oriented layering of these molecules. Characterization by optical ellipsometry and grazing angle X-ray diffraction provides insight on average layer thicknesses and bulk film densities. Second harmonic generation (SHG) intensity from the bulk film is measured to verify NLO activity.


Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below.

References

1. Netzer, L., Sagiv, J., J. Am. Chem. Soc., 105, 674 (1983).Google Scholar
2. Maoz, R., Netzer, L., Gun, J., Sagiv, J., J. Chem. Phys., 85, 1059 (1988).Google Scholar
3. Tillman, N., Ulman, A., Penner, T.L., Langmuir, 5, 101 (1989).CrossRefGoogle Scholar
4. Li, D., Ratner, M.A., Marks, T.J., Zhang, C., Yang, J., Wong, G. J., J. Am. Chem. Soc., 112, 7389 (1990).CrossRefGoogle Scholar
5. Lee, H., Kepley, L.J., Hong, H.-G., Mallouk, T.E., J. Am. Chem. Soc., 110, 618 (1988).CrossRefGoogle Scholar
6. Lee, H., Kepley, L.J., Hong, H.-G., Akhter, S., Mallouk, T.E., J. Phys. Chem., 92, 2597 (1988).CrossRefGoogle Scholar
7. Katz, H.E., Scheller, G., Putvinski, T.M., Schilling, M.L., Wilson, W.L., C.E.D. Chidsey, Science, 254, 1485 (1991).Google Scholar
8. Yang, H.C., Aoki, K., Hong, H., Sackett, D.D., Rendt, M.F., Yau, S., Bell, C.M., and Mallouk, T.E., J. Am. Chem. Soc., 115, 11855 (1993).CrossRefGoogle Scholar
9. Vermuelen, L.A., Snover, J.L., Sapochak, L.S., Thompson, M.E., J. Am. Chem. Soc., 115, 11767 (1993).CrossRefGoogle Scholar
10. Katz, H.E., Chem. Mater., 6, 2227, (1994).CrossRefGoogle Scholar
11. Zeppenfeld, A.C., Fiddler, S.L., Ham, W.K., Klopfenstein, B.J., Page, C.J., J. Am. Chem. Soc., 116, 9158 (1994).CrossRefGoogle Scholar
12. Zeppenfeld, A.C., Page, C. J., Mater. Res. Soc. Symp. Proc. 351, 77 (1994), Molecularly Designed Ultrafine/Nanostructured Materials, Gonsalves, K.E., Chow, G.-M., Xiao, T.D., Cammarata, R.C., Editors, Materials Research Society, Pittsburgh, PA. Google Scholar
13. Neff, G.A., Zeppenfeld, A.C., Klopfenstein, B.J., Page, C. J., Mater. Res. Soc. Symp. Proc., 351, 269 (1994), Molecularly Designed Ultrafine/Nanostructured Materials, Gonsalves, K.E., Chow, G.-M., Xiao, T.D., Cammarata, R.C., Editors, Materials Research Society, Pittsburgh, PA.CrossRefGoogle Scholar
14. O'Brien, J.T., Zeppenfeld, A.C., Richmond, G.L., Page, C.J., Langmuir, 10, 4657 (1994).CrossRefGoogle Scholar
15. Neff, G.A., Page, C.J., Meintjes, E., Tsuda, T., Pilgrim, W.-C., Roberts, N., Warren, W.W. Jr., Langmuir, 12, 238 (1996).CrossRefGoogle Scholar
16. Ansell, M.A., Cogan, E.B., Neff, G.A., Page, C.J., submitted to Supramolecular Science.Google Scholar
17. Ansell, M.A., Zeppenfeld, A.C., Ham, W.K., Page, C.J., Mater. Res. Soc. Symp. Proc., 351, 171 (1994), Materials Research Society, Pittsburgh, PA.Google Scholar
18. Ansell, M.A., Zeppenfeld, A.C., Yoshimoto, K., Cogan, E.B., Page, C.J., Chem. Mater., 8, 591 (1996).CrossRefGoogle Scholar
19. Dines, M.B., DiGiacomo, P.M., Inorg. Chem., 20, 92 (1981).CrossRefGoogle Scholar
20. Cao, G., Hong, H.-G., Mallouk, T.E., Acc. Chem. Res., 25, 420 (1992).CrossRefGoogle Scholar
21. Engel, R.E., Synthesis of Carbon-Phosphorus Bonds, CRC Press, Boca Raton, FL, p.21 (1988).Google Scholar
22. Unpublished results.Google Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 0
Total number of PDF views: 5 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 4th December 2020. This data will be updated every 24 hours.

Hostname: page-component-b4dcdd7-9fdqb Total loading time: 0.323 Render date: 2020-12-04T20:15:54.387Z Query parameters: { "hasAccess": "0", "openAccess": "0", "isLogged": "0", "lang": "en" } Feature Flags last update: Fri Dec 04 2020 19:59:42 GMT+0000 (Coordinated Universal Time) Feature Flags: { "metrics": true, "metricsAbstractViews": false, "peerReview": true, "crossMark": true, "comments": true, "relatedCommentaries": true, "subject": true, "clr": false, "languageSwitch": true }

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Second Harmonic Generation from Multilayers of Oriented Metal Bisphosphonates
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Second Harmonic Generation from Multilayers of Oriented Metal Bisphosphonates
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Second Harmonic Generation from Multilayers of Oriented Metal Bisphosphonates
Available formats
×
×

Reply to: Submit a response


Your details


Conflicting interests

Do you have any conflicting interests? *