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Room-Temperature Synthesis and Electrical Properties of La, Nd and Gd Apatite-type Silicates
Published online by Cambridge University Press: 26 February 2011
Abstract
We show in this paper the possibility of using mechanical milling to prepare apatite-type La, Nd and Gd silicates starting from stoichiometric mixtures of the constituent oxides. XRD patterns collected after grinding the starting mixtures for 9 hours contain only the characteristic reflections of the target materials with no other phase apparently present. Electrical conductivity data were successfully fitted to a Jonscher-type empirical expression with fractional exponent n included in the 0.35-0.75 range. Activation energies for oxygen migration were found to decrease as the size of the rare-earth cation increases. Therefore, the highest conductivity values were found for the apatite-type lanthanum silicate.
- Type
- Research Article
- Information
- MRS Online Proceedings Library (OPL) , Volume 972: Symposium AA – Solid-State Ionics—2006 , 2006 , 0972-AA09-05
- Copyright
- Copyright © Materials Research Society 2007
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