Skip to main content Accessibility help

We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.

Close cookie message
×
Home
  • Home
Hostname: page-component-559fc8cf4f-q7jt5 Total loading time: 0.211 Render date: 2021-02-28T07:14:16.993Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false, "newCitedByModal": true }
EnglishFrançais
MRS Online Proceedings Library (OPL) MRS Online Proceedings Library (OPL)

Article contents

Redox Behavior of Palladium Ion in Oxide Glasses

Published online by Cambridge University Press:  15 February 2011

Masaru Yamashita ,
Junji Nishii ,
Tomoko Akai  and
Hiroshi Yamanaka
Masaru Yamashita
Affiliation:
Department of Optical Materials, Osaka National Research Institute, AIST., 1–8-3 1, Midorigaoka, Ikeda, 563 Japan, yamashita_m@onri.go.jp
Junji Nishii
Affiliation:
Department of Optical Materials, Osaka National Research Institute, AIST., 1–8-3 1, Midorigaoka, Ikeda, 563 Japan, yamashita_m@onri.go.jp
Tomoko Akai
Affiliation:
Department of Optical Materials, Osaka National Research Institute, AIST., 1–8-3 1, Midorigaoka, Ikeda, 563 Japan, yamashita_m@onri.go.jp
Hiroshi Yamanaka
Affiliation:
Department of Optical Materials, Osaka National Research Institute, AIST., 1–8-3 1, Midorigaoka, Ikeda, 563 Japan, yamashita_m@onri.go.jp
Corresponding
E-mail address:
yamashita_m@onri.go.jp
Get access

Abstract

Reduction and separation of Pd were investigated in soda-lime-alumino-borosilicate glass. The dependence on raw materials, melting atmosphere, concentration of Pd and melting temperature was examined by electrochemical oxygen activity measurement, optical absorbance, X-ray diffraction and microscopic observation. Pd ions were slowly reduced during melting and metal particles were formed. The separation was enhanced in a reducing atmosphere, at high temperature, for long melting periods and with high concentration of Pd. Pd metal particles of about 10 to 30 μm in diameter were observed by SEM and X-ray diffraction.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 412: Symposium V – Scientific Basis for Nuclear Waste Management XIX , 1995 , 157
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below.
If you should have access and can't see this content please contact technical support.

References

1. Radioactive Waste Forms For The Future, edited by Lutze, W. and Ewing, R. C., North Holland Physics Publishing, 1988, pp. 1–159.Google Scholar
2. Kelm, K., Görtzen, A., Kleykamp, H. and Pentinghaus, H., J. Less-Common Metals 166, p. 125 (1990).CrossRefGoogle Scholar
3. Krause, C. and Luckscheiter, B., J. Mater. Res. 6, p. 2, 535 (1991).CrossRefGoogle Scholar
4. Schreiber, H. D., Harville, T. R. and Damron, G. N., J. Am. Ceram. Soc. 73, p. 1,435 (1990).CrossRefGoogle Scholar
5. Lenhart, V. A. and Schaeffer, H. A., Glastech. Ber. 58, p. 139 (1985).Google Scholar
6. Freude, E. and Rüssel, C., Glastech. Ber. 60, p. 202 (1987).Google Scholar
7. Freude, E., Lutze, W., Rüssel, C. and Schaeffer, H. A. in Scientific Basis for Nuclear Waste Management XII, edited by Lutze, W. and Ewing, R. C. (Mater. Res. Soc. Proc. 127, Pittsburgh, PA 1989), p. 199–204.Google Scholar
8. Yamanaka, H., Nishii, J., Akai, T., Yamashita, M. and Wakabayashi, H. in Scientific Basis for Nuclear Waste Management XVIII, edited by Murakami, T. and Ewing, R. C. (Mater. Res. Soc. Proc. 353, Pittsburgh, PA 1995), p. 95–100.Google Scholar
9. Rindone, G. E. and Rhoads, J. L., J. Am. Ceram. Soc. 39, p. 173 (1956).CrossRefGoogle Scholar
10. Ayres, G. H. and Martin, J. B., Anal. Chim. Acta 35, p. 181 (1966).CrossRefGoogle Scholar
11. Johnston, W. D., J. Am. Ceram. Soc. 48, p. 184 (1965).CrossRefGoogle Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 0
Total number of PDF views: 7 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 28th February 2021. This data will be updated every 24 hours.

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Redox Behavior of Palladium Ion in Oxide Glasses
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Redox Behavior of Palladium Ion in Oxide Glasses
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Redox Behavior of Palladium Ion in Oxide Glasses
Available formats
×
×

Reply to: Submit a response

Your details

Conflicting interests

Do you have any conflicting interests? *