Skip to main content Accessibility help

We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.

Close cookie message
×
Home
  • Home
EnglishFrançais
MRS Online Proceedings Library (OPL) MRS Online Proceedings Library (OPL)

Article contents

Occupied and Unoccupied Orbitals of C60 and C70 Probed with C 1s Emission and Absorption

Published online by Cambridge University Press:  22 February 2011

J. A. Carlisle ,
L. J. Terminello ,
E. A. Hudson ,
E.L. Shirley ,
F. J. Himpsel ,
J. J. Jia ,
T. A. Callcott ,
R. C. C. Perera ,
S. G. Louie ,
J. StÖhr ,
M. G. Samant  and
D. L. Ederer
J. A. Carlisle
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
L. J. Terminello
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
E. A. Hudson
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
E.L. Shirley
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
F. J. Himpsel
Affiliation:
IBM Research Division, Thomas J. Watson Research Center, Yorktown Heights, NY 10598
J. J. Jia
Affiliation:
University of Tennessee, Knoxville, TN 37996
T. A. Callcott
Affiliation:
University of Tennessee, Knoxville, TN 37996
R. C. C. Perera
Affiliation:
Lawrence Berkeley Laboratory, Berkeley, CA 94720
S. G. Louie
Affiliation:
Lawrence Berkeley Laboratory, Berkeley, CA 94720
J. StÖhr
Affiliation:
Department of Physics, U.C. Berkeley, CA 94720
M. G. Samant
Affiliation:
IBM Research Division, Almaden Research Center, 650 Harry Road, San Jose, CA 95120-6099
D. L. Ederer
Affiliation:
Tulane University, New Orleans, LA, 70118
Get access

Abstract

The full spectrum of occupied and unoccupied σ and Π orbitals is presented for solid C60, C70, and graphite, using C1s emission and absorption spectroscopy. There are significant differences between C60 and C70, and even larger changes relative to their infinite analog graphite C∞. A comparison is made with photoemission and inverse photoemission results, along with first principles quasiparticle calculations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 349: Symposium T – Novel Forms of Carbon II , 1994 , 245
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below.
If you should have access and can't see this content please contact technical support.

References

[1] Weaver, J.H., J. Phys. Chem. Solids 53, 1433 (1992).CrossRefGoogle Scholar
[2] Briihwiler, P.A., Maxwell, A.J., Nilsson, A., Whetten, R.L., and Mèrtensson, N., Chem. Phys. Lett. 193, 311 (1992).CrossRefGoogle Scholar
[3] Takahashi, T., Suzuki, S., Morikawa, T., Katayama-Yoshida, H., Hasegawa, S., Inokuchi, H., Seki, K., Kikuchi, K., Suzuki, S., Ikemoto, K., and Achiba, Y., Phys. Rev. Lett. 68, 1232 (1992).CrossRefGoogle Scholar
[4] Terminello, L.J., Shuh, D.K., Himpsel, F.J., Lapiano-Smith, D.A., Stöhr, J., Bethune, D.S., and Meijer, G., Chem. Phys. Lett. 182, 491 (1991).CrossRefGoogle Scholar
[5] Glans, Peter, PhD thesis, Uppsala University (1993).Google Scholar
[6] Wiech, G., in: Inner-Shell and X-Ray Physics of Atoms and Solids, ed. by Fabian, D.J., Kleinpoppen, H., and Watson, L.W., Plenum (New York 1981), p. 815. These graphite data have been used to calibrate the photon energy in our emission spectrograph. Using Ref. 5 as calibration our energies for the emission spectra would be about 1 eV higher.CrossRefGoogle Scholar
[7] Shirley, E.L. and Louie, S.G., Phys. Rev. Lett. 71, 133 (1993).CrossRefGoogle Scholar
[8] Trouillier, N. and Martins, J.L., Phys. Rev. B 46, 1754 (1992).CrossRefGoogle Scholar
[9] Haddon, R.C., Science 261, 1545 (1993).CrossRefGoogle Scholar
[10] Burstein, E., Erwin, S.C., Jiang, M.Y., and Messmer, R.P., Physica Scripta T42, 207 (1992).CrossRefGoogle Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 0
Total number of PDF views: 7 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 26th January 2021. This data will be updated every 24 hours.

2 Cited by
Hostname: page-component-898fc554b-t2lmn Total loading time: 0.267 Render date: 2021-01-26T16:18:44.223Z Query parameters: { "hasAccess": "0", "openAccess": "0", "isLogged": "0", "lang": "en" } Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false }

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Occupied and Unoccupied Orbitals of C60 and C70 Probed with C 1s Emission and Absorption
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Occupied and Unoccupied Orbitals of C60 and C70 Probed with C 1s Emission and Absorption
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Occupied and Unoccupied Orbitals of C60 and C70 Probed with C 1s Emission and Absorption
Available formats
×
×

Reply to: Submit a response

Your details

Conflicting interests

Do you have any conflicting interests? *