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New Routes to Group Iva Metal-Nitrides

Published online by Cambridge University Press:  25 February 2011

Chaitanya K. Narula
Affiliation:
Department of Chemistry, Research Laboratory, Ford Motor Company, P.O. Box 2053, MD 3083, Dearborn, Ml 48121
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Abstract

The reactions of TiCl4 with [(CH3)3Si]2NH have been examined under several reaction conditions. One of the reaction products, (CH3)3Si(H)NTiCl3, can be crystallized in 60% yield on reacting TiCl4 with TiCl4 with [(CH3)3Si]2NH in a 1:1 molar ratio in dichloromethane at -78°C. [(CH3)3Si(H)NTi(Cl2)(NH)]2TiCl2 is the primary product on increasing the amount of TiCl4 with [(CH3)3Si]2NH to two equivalents. (CH3)3Si(H)NTiCl3 and [(CH3)3Si(H)NTi(Cl2)(NH)]2TiCl2 form titanium nitride on pyrolysis at 600°C in an ammonia atmosphere.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

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