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Meso-scale Order Structure Prepared From Immiscible Polymer Blend Solutions

Published online by Cambridge University Press:  13 March 2014

Junhyeok Jang
Affiliation:
Department of Applied Chemistry, Graduate School of Urban Environmental Science, Tokyo Metropolitan University, 1-1 Minami-Osawa Hachioji Tokyo 192-0397, Japan
Tsuyoshi Inoue
Affiliation:
Department of Applied Chemistry, Graduate School of Urban Environmental Science, Tokyo Metropolitan University, 1-1 Minami-Osawa Hachioji Tokyo 192-0397, Japan
Masayuki Kawazoe
Affiliation:
Research Center, Yokohama Rubber Co. Ltd. Oiwake, Hiratsuka, Kanagawa, Japan
Hirohisa Yoshida
Affiliation:
Department of Applied Chemistry, Graduate School of Urban Environmental Science, Tokyo Metropolitan University, 1-1 Minami-Osawa Hachioji Tokyo 192-0397, Japan
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Abstract

The meso-scale hexagonally packed order structures were obtained by solvent casting from the immiscible polymer blend solutions. The order structures were the result of phase separation occurred at the evaporation front during the solvent casting, the so-called dissipative system. The order domains were flat spheres or ellipses on the matrix surface depending on the combination of polymer blends and solvent, the diameter of spheres were tunable from 0.5 to 3 μm by the casting condition, such as the solvent used for mixing and the evaporation rate. Three blend systems, NBR/SBR, NBR/BR and PMMA/BR, formed two dimensional order structures with the domain size in μm-scale by solvent casting from those homogeneous solutions. The conditions to obtain the two dimensional meso-scale order structure were evaluated.

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Copyright
Copyright © Materials Research Society 2014 

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