Skip to main content Accessibility help

We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.

Close cookie message
×
Home
  • Home
Hostname: page-component-559fc8cf4f-8sgpw Total loading time: 0.473 Render date: 2021-03-03T15:57:18.286Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false, "newCitedByModal": true }
EnglishFrançais
MRS Online Proceedings Library (OPL) MRS Online Proceedings Library (OPL)

Article contents

Matrix-Assisted Synthesis of Palladium Nanocage and Nanowires

Published online by Cambridge University Press:  17 March 2011

Jinwoo Cheon ,
Kyung-Bok Lee ,
Hongkyu Kang ,
S. J. Oh  and
H.-C. Ri
Kyung-Bok Lee
Affiliation:
Department of Chemistry and School of Molecular Science-BK21, Korea Advanced Institute of Science and Technology (KAIST), Taejon, 305-701, Korea
Hongkyu Kang
Affiliation:
Department of Chemistry and School of Molecular Science-BK21, Korea Advanced Institute of Science and Technology (KAIST), Taejon, 305-701, Korea
S. J. Oh
Affiliation:
Korea Basic Science Institute (KBSI), Taejon, 305-333, Korea
H.-C. Ri
Affiliation:
Korea Basic Science Institute (KBSI), Taejon, 305-333, Korea
Get access

Abstract

Our study describes the synthesis of novel nanoscale Pd cage and wires whose sizes and shapes are templated by mesoporous matrices. The templates used are cubic phase MCM-48 and hexagonal phase CnMCM-41 (n = 16, and 22), SBA-15, which have pore diameters of ∼3, ∼3.8, ∼4.7, and ∼9 nm, respectively. For Pd@MCM-48, the Pd metal forms spherical domains (∼38 nm) consisting of three dimensionally interconnected into Pd arrays; for Pd@SBA-15 and Pd@MCM-41, the Pd metal forms of one-dimensional wires. Etching out the matrix produces porous Pd cages (pore sizes of ∼1.5 - 2.0 nm) with retaining original domain sizes of ∼38 nm; similarly Pd@SBA-15 and Pd@MCM-41 afford freestanding Pd nanowires. All the materials are examined by TEM, XRD, BET, and EDAX analysis. Furthermore, the thermal behavior of Pd nanowire is briefly described.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 635: Symposium C – Anisotropic Nanoparticles-Synthesis, Characterization & Applications , 2001 , C3.3
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below.
If you should have access and can't see this content please contact technical support.

References

1. Alivisatos, A. P., Science, 271, 933 (1996).CrossRefGoogle Scholar
2. a) Wu, C. and Bein, T., Science, 264, 1757 (1994). b) C. Wu and T. Bein, Science, 266, 1013 (1994). c) C. R. Martin, Chem. Mater., 8, 1739 (1996).CrossRefGoogle Scholar
3. Ying, J. Y., Mehnert, C. D. and Wong, M. S., Angew. Chem., Int. Ed. Engl., 38, 56 (1999).3.0.CO;2-E>CrossRefGoogle Scholar
4. Johnson, S. A., Ollovier, P. J. and Mallouk, T. E., Science, 283, 963 (1999).CrossRefGoogle Scholar
5. Ryoo, R., Joo, S. H. and Jun, S.,J. Phys. Chem. B, 103, 7743 (1999).CrossRefGoogle Scholar
6. Attard, G. S., Bartlett, P. N., Coleman, R. B., Elliott, J. M., Owen, J. R. and Wang, J. H., Science, 278, 838 (1997).CrossRefGoogle Scholar
7. a) Han, Y. J., Kim, J. and Stucky, G. D., Chem. Mater., 12, 2068 (2000). b) M. H. Huang, A. Choudrey and P. Yang, Chem. Commun. 1063 (2000). c) H. Kang, Y. Jun, J.-I. Park, K.-B. Lee, and J. Cheon, Chem. Mater., 12, 3530 (2000).CrossRefGoogle Scholar
8. Velev, O. D., Tessier, P. M., Lenhoff, A. M. and Kaler, E. W., Nature, 401, 548 (1999).CrossRefGoogle Scholar
9. McGraw-Hill Concise Encyclopedia of Science and Technology, ed. Parker, S. P. (McGraw- Hill: New York, 1989) pp.1343.Google Scholar
10. The cubic MCM-48 and hexagonal SBA-15 hosts were prepared by a literature method. See: Zhao, D., Feng, J., Huo, Q., Melosh, N., Fredrickson, G. H., Chmelka, B. F. and Stucky, G. D., Science, 279, 548 (1998).CrossRefGoogle Scholar
11. Pd(hfac)2 was synthesized following a literature method. See: Siedle, A. R., Newmark, R. A., Kruger, A. A., Pignolet, L. H., Inorg. Chem., 20, 3399 (1981).CrossRefGoogle Scholar
12. Pd(hfac)2 is known to adsorb readily on silica surfaces by means of strong Lewis acid-base interactions between the Pd center and surface hydroxyl groups. See: Siedle, A. R. and Newmark, R. A., J. Am. Chem. Soc., 103, 1240 (1981).CrossRefGoogle Scholar
13. Conners, L., Hollis, T., Johnson, D. A. and Blyholder, G., J. Phys. Chem. B, 102, 10112 (1998).CrossRefGoogle Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 0
Total number of PDF views: 10 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 3rd March 2021. This data will be updated every 24 hours.

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Matrix-Assisted Synthesis of Palladium Nanocage and Nanowires
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Matrix-Assisted Synthesis of Palladium Nanocage and Nanowires
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Matrix-Assisted Synthesis of Palladium Nanocage and Nanowires
Available formats
×
×

Reply to: Submit a response

Your details

Conflicting interests

Do you have any conflicting interests? *