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Ink-jet Printed BaTiO3 for Photonics

Published online by Cambridge University Press:  28 May 2012

Petra Lommens
Affiliation:
SCRiPTS, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 – S3, 9000 Gent, Belgium.
Tom Bruggeman
Affiliation:
SCRiPTS, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 – S3, 9000 Gent, Belgium.
Glenn Pollefeyt
Affiliation:
SCRiPTS, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 – S3, 9000 Gent, Belgium.
Melis Arin
Affiliation:
SCRiPTS, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 – S3, 9000 Gent, Belgium.
Jonas Feys
Affiliation:
SCRiPTS, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 – S3, 9000 Gent, Belgium.
Isabel Van Driessche
Affiliation:
SCRiPTS, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 – S3, 9000 Gent, Belgium.
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Abstract

A water-based BaTiO3 precursor solution, suited for ink-jet printing of hetero-epitaxial BaTiO3 layers on LaAlO3 single-crystal substrates was developed. First, a study on the simultaneous stabilization of Ba2+ and Ti4+ions in a neutral, aqueous environment was performed. Thermal analysis of the precursor was used to select appropriate temperature programs and the rheology of the solutions is studied to optimize dipcoating and later ink-jet printing parameters. On both substrates, it was possible to obtain epitaxial layers of about 200 nm thickness after sintering at temperatures above 1000 °C. Currently, we are adapting the thermal program and heating atmosphere in order to reduce the sintering temperatures, decrease the surface roughness and increase density.

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Articles
Copyright
Copyright © Materials Research Society 2012

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References

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