Skip to main content Accessibility help

We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.

Close cookie message
×
Home
  • Home
Hostname: page-component-78dcdb465f-fqvcn Total loading time: 0.307 Render date: 2021-04-19T16:10:20.408Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false, "newCitedByModal": true }
EnglishFrançais
MRS Online Proceedings Library (OPL) MRS Online Proceedings Library (OPL)

Article contents

Effects of Molecular Rigidity on Electric Field Induced Alignment and Orientational Stability of Dipolar Chromophore Composites

Published online by Cambridge University Press:  25 February 2011

H. E. Katz ,
M. L. Schilling ,
G. Washington ,
C. W. Dirk ,
W. R. Holland ,
T. Fang  and
K. D. Singer
H. E. Katz
Affiliation:
AT&T Bell Laboratories 1D-250, 600 Mountain Avenue, Murray Hill, NJ 07974 and Princeton, NJ 08540
M. L. Schilling
Affiliation:
AT&T Bell Laboratories 1D-250, 600 Mountain Avenue, Murray Hill, NJ 07974 and Princeton, NJ 08540
G. Washington
Affiliation:
AT&T Bell Laboratories 1D-250, 600 Mountain Avenue, Murray Hill, NJ 07974 and Princeton, NJ 08540
C. W. Dirk
Affiliation:
AT&T Bell Laboratories 1D-250, 600 Mountain Avenue, Murray Hill, NJ 07974 and Princeton, NJ 08540
W. R. Holland
Affiliation:
AT&T Bell Laboratories 1D-250, 600 Mountain Avenue, Murray Hill, NJ 07974 and Princeton, NJ 08540
T. Fang
Affiliation:
AT&T Bell Laboratories 1D-250, 600 Mountain Avenue, Murray Hill, NJ 07974 and Princeton, NJ 08540
K. D. Singer
Affiliation:
AT&T Bell Laboratories 1D-250, 600 Mountain Avenue, Murray Hill, NJ 07974 and Princeton, NJ 08540
Get access

Abstract

The relationship between the supramolecular conformational structure of assembled chromophores and their susceptibility to electric field poling is of interest for maximizing the bulk alignment achievable in an electro-optic material. We have employed solution phase dielectric constant measurements to investigate possible enhancements in dipolar susceptibility as a function of connectivity and state of aggregation in rationally synthesized chromophore assemblies, including conformationally defined head-to-tail oligomers. On the other hand, conformationally unrestricted, highly dipolar azo dyes behave as relatively isolated molecules even when present in supersaturated solutions and in close proximity on polymer chains.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 173: Symposium Q – Advanced Organic Solid State Materials , 1989 , 543
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below.
If you should have access and can't see this content please contact technical support.

References

1. Singer, K.D., Kuzyk, M.G., Holland, W.R., Sohn, J.E., Lalama, S.J., Comizzoli, R.B., Katz, H.E., and Schilling, M.L.. Appl. Phys. Lett. 53, 1800 (1988).CrossRefGoogle Scholar
2. Katz, H.E., Singer, K.D., Sohn, J.E., Dirk, C.W., King, L.A., Gordon, H.M.. J. Am. Chem. Soc. 109, 6561 (1987).CrossRefGoogle Scholar
3. Williams, D.J., Hall, H.K., et al. Macromoleules, 20, 716, 722 (1987)Google Scholar
Willand, C.S., Williams, D.J.. Ber. Bunsen. Phys. Chem., 91, 1304 (1987).CrossRefGoogle Scholar
4. Schilling, M.L., Katz, H.E., Cox, D.I.. J. Org. Chem. 53 5538 (1988).CrossRefGoogle Scholar
5. Bottcher, C.J., “Theory of Electric Polarization” (Elsevier, Amsterdam 1952).Google Scholar
6. Onsager, L.. J. Am. Chem. Soc. 58, 1456 (1936).CrossRefGoogle Scholar
7. Singer, K.D., Kuzyk, M.G., Sohn, J.E.. J. Opt. Sci. Am. B. 4, 968 (1987).CrossRefGoogle Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 0
Total number of PDF views: 4 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 19th April 2021. This data will be updated every 24 hours.

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Effects of Molecular Rigidity on Electric Field Induced Alignment and Orientational Stability of Dipolar Chromophore Composites
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Effects of Molecular Rigidity on Electric Field Induced Alignment and Orientational Stability of Dipolar Chromophore Composites
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Effects of Molecular Rigidity on Electric Field Induced Alignment and Orientational Stability of Dipolar Chromophore Composites
Available formats
×
×

Reply to: Submit a response

Your details

Conflicting interests

Do you have any conflicting interests? *