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Angle Resolved Thermal Desorption Studies for Poly(methylvinylidene cyanide) and Poly(vinylidenefluoride trifluoroethylene)

Published online by Cambridge University Press:  01 February 2011

Carolina C. Ilie
Affiliation:
cilie@unlserve.unl.edu, University of Nebraska at Lincoln, Physics and Astronomy, 116 Brace Laboratory of Physics, University of Nebraska at Lincoln, Lincoln, NE, 68588-0111, United States
P. A. Jacobson
Affiliation:
pjacobso@tulane.edu, University of Nebraska at Lincoln, Physics and Astronomy, 116 Brace Laboratory of Physics, Lincoln, NE, 68588-0111, United States
Matt Poulsen
Affiliation:
mpoulsen@bigred.unl.edu, University of Nebraska at Lincoln, Physics and Astronomy, 116 Brace Laboratory of Physics, Lincoln, NE, 68588-0111, United States
Luis G. Rosa
Affiliation:
lgrosa@princeton.edu, University of Nebraska at Lincoln, Physics and Astronomy, 116 Brace Laboratory of Physics, Lincoln, NE, 68588-0111, United States
D. Sahadeva-Reddy
Affiliation:
jtakacs@unlserve.unl.edu, University of Nebraska at Lincoln, Chemistry, 552 Hamilton Hall, Lincoln, NE, 68588-0304, United States
James M. Takacs
Affiliation:
jtakacs@unlserve.unl.edu, University of Nebraska at Lincoln, Chemistry, 552 Hamilton Hall, Lincol n, NE, 68588-0304, United States
Stephen Ducharme
Affiliation:
sducharme1@unl.edu, University of Nebraska at Lincoln, Physics and Astronomy, 116 Brace Laboratory of Physics, Lincoln, NE, 68588-0111, United States
P. A. Dowben
Affiliation:
pdowben@unl.edu, University of Nebraska at Lincoln, Physics and Astronomy, 116 Brace Laboratory of Physics, Lincoln, NE, 68588-0111, United States
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Abstract

We compare water adsorption and desorption on ferroelectric copolymer poly(vinylidene fluoride-trifluoroethylene), and the dipole ordered polymer poly(methylvinylidene cyanide). The angle-resolved thermal desorption spectra prove that the absorbed water species interacts more strongly with poly(vinylidene fluoride-trifluoroethylene) than with poly(methylvinylidene cyanide). The angle resolved thermal desorption spectra shows large deviations from the cosine distribution for light illuminated poly(vinylidene fluoride-trifluoroethylene). Water desorption from poly(methylvinylidene cyanide) deviates from the cosine distribution without illumination.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

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References

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Angle Resolved Thermal Desorption Studies for Poly(methylvinylidene cyanide) and Poly(vinylidenefluoride trifluoroethylene)
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