Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-17T21:48:19.343Z Has data issue: false hasContentIssue false
  • English
  • Français

Ab-initio Studies of Plutonium with Relevance to Nuclear Waste Management

Published online by Cambridge University Press:  11 February 2011

Arun K. Setty ,
B. R. Cooper  and
D. L. Price
Arun K. Setty
Affiliation:
Department of Physics, West Virginia University, Morgantown, WV
B. R. Cooper
Affiliation:
Department of Physics, West Virginia University, Morgantown, WV
D. L. Price
Affiliation:
University of Memphis, Memphis, Tennessee (deceased)
Get access

Abstract

Plutonium, well known for its unusual nuclear and material properties, has remained an unsolved problem for over a half century. Due to the continuing issue of safe, longterm nuclear waste storage, gaining an understanding of plutonium and its compounds cannot be overstated. Self-irradiation in plutonium leads to vacancy formation [1], and our computations indicate that the electronic structure we predict for pure delta plutonium is preserved in the presence of vacancies, and that vacancies do stabilize the delta phase. A preliminary study of self-diffusive properties of plutonium, and of diffusion at the interface of plutonium and iron indicates that plutonium atoms readily diffuse across the interface with steel. This has relevance in nuclear waste storage in steel containers for assessing the depth of penetration to be dealt with in surface treatment for decontamination. The effect of thermomigration (Soret effect) in the plutonium-steel system appears to facilitate the movement of plutonium atoms into the bulk steel.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 757: Symposium II – Scientific Basis for Nuclear Waste Management XXVI , 2002 , II3.32
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Fluss, M. et al., private communication.Google Scholar
2. Cooper, B. R. et al, Phil. Mag. B 79, 683 (1999);Google Scholar
Cooper, B.R., Los Alamos Science 26, 106 (2000)); B.R. Cooper, A.K. Setty and D.L. Price, to be published.Google Scholar
3. Dormeval, M. et al., private communication (2001).Google Scholar
4. Hecker, S. S., MRS Bulletin 26, 672, (2001).Google Scholar
5. Arko, A. J., Joyce, J. J., Morales, L., Wills, J., and Lashley, J. et. al., Phys. Rev B, 62, 1773 (2000).Google Scholar
6. Krakauer, H., Cooper, B. R., Phys. Rev. B 16, 605 (1977).Google Scholar
7. Wills, J. M., Cooper, B. R., Phys. Rev. B 36, 3809 (1987);Google Scholar
Wills, J. M., Cooper, B. R., Phys. Rev. B 42, 4652 (1990).Google Scholar
8. Price, D. L., Phys. Rev. B 60, 10588 (1999);Google Scholar
Perdew, J. P., Zunger, A., Phys. Rev. B 23, 5048 (1981).Google Scholar
9. Wade, W.Z. et al, Metallurgical Transactions A, 965 (1978).Google Scholar
10. Stark, J.P., Solid State Diffusion, (John Wiley and Sons, New York, 1978).Google Scholar
11. McKee, R.A. and Stark, J.P., Phys. Rev. B11, 1374 (1975).Google Scholar