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Semiconducting Block Copolymers for Self-Assembled Photovoltaic Devices

Published online by Cambridge University Press:  31 January 2011

Georges Hadziioannou
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Abstract

This article focuses on self-assembled photovoltaic materials based on a new class of semiconducting block copolymers for application in photovoltaic devices. Topics discussed include the materials concept for efficient photovoltaic-device structures, their macromolecular design and synthesis, and their performance in relation to their molecular, mesoscopic, and interfacial structures. An ideal organic material for this application would have to compete with amorphous silicon in regard to energy-conversion efficiency and fabrication costs. The potential of the semiconducting block copolymers presented in this review lies in the promise of large-area, mechanically flexible, self-structured photovoltaic devices fabricated by inexpensive processing techniques.

Keywords

electroactive organic materialsorganic semiconductor–metal interfacesphotovoltaic devicesself-assemblysemiconducting block copolymerssuperstructures.
Type
Research Article
Information
MRS Bulletin , Volume 27 , Issue 6: Electroactive Organic Materials , June 2002 , pp. 456 - 460
Copyright
Copyright © Materials Research Society 2002

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References

1.Chiang, C.K., Fincher, C.R., Park, Y.W., Heeger, A.J., Shirakawa, H., Louis, E.J., Gau, S.C., and MacDiarmid, A.G., Phys. Rev. Lett. 39 (1977) p. 1098.CrossRefGoogle Scholar
2.Heeger, A.J., Angew. Chem., Int. Ed. Engl. 40 (2001) p. 2591.3.0.CO;2-0>CrossRefGoogle Scholar
3.Burroughes, J.H., Bradley, D.D.C., Brown, A.R., Marks, R.N., MacKay, K., Friend, R.H., Burn, P.L., and Holmes, A.B., Nature 347 (1990) p. 539.CrossRefGoogle Scholar
4.Heeger, A.J., MRS Bull. 26 (11) (2001) p. 900.CrossRefGoogle Scholar
5.Friend, R.H., Burroughes, J.H., and Shimoda, T., Phys. World 12 (6) (1999) p. 35.CrossRefGoogle Scholar
6.Bao, Z., Adv. Mater. 12 (2000) p. 227.3.0.CO;2-U>CrossRefGoogle Scholar
7.Kraft, A., Grimsdale, A.C., and Holmes, A.B., Angew. Chem., Int. Ed. Engl. 37 (1998) p. 402.3.0.CO;2-9>CrossRefGoogle Scholar
8.Sariciftci, N.S., Smilowitz, L., Heeger, A.J., and Wudl, F., Science 258 (1992) p. 1474.CrossRefGoogle Scholar
9.Yu, G., Gao, J., Hummelen, J.C., Wudl, F., and Heeger, A.J., Science 270 (1995) p. 1789.CrossRefGoogle Scholar
10.Halls, J.J.M., Walsh, C.A., Greenham, N.C., Marseglia, E.A., Friend, R.H., Moratti, S.C., and Holmes, A.B., Nature 376 (1995) p. 498.CrossRefGoogle Scholar
11.Bates, F.S. and Fredrickson, G.H., Annu. Rev. Phys. Chem. 41 (1990) p. 525.CrossRefGoogle Scholar
12.Stalmach, U., de Boer, B., Videlot, C., van Hutten, P.F., and Hadziioannou, G., J. Am. Chem. Soc. 122 (2000) p. 5464.CrossRefGoogle Scholar
13.Eckert, J.-F., Nicoud, J.-F., Nierengarten, J.-F., Liu, S.-G., Echegoyen, L., Barigelletti, F., Armaroli, N., Ouali, L., and Krasnikov, V., J. Am. Chem. Soc. 122 (2000) p. 7467.CrossRefGoogle Scholar
14.Ouali, L., Krasnikov, V.V., Stalmach, U., and Hadziioannou, G., Adv. Mater. 11 (1999) p. 1515.3.0.CO;2-A>CrossRefGoogle Scholar
15.Schmidt-Mende, L., Fechtenkötter, A., Müllen, K., Moons, E., Friend, R.H., and MacKenzie, J.D., Science 293 (2001) p. 1119.CrossRefGoogle Scholar
16.Schatz, M.F., VanHook, S.J., McCormick, W.D., Swift, J.B., and Swinney, H.L., Phys. Rev. Lett. 75 (1995) p. 1938.CrossRefGoogle Scholar
17.Widawski, G., Rawiso, M., and François, B., Nature 369 (1994) p. 387.CrossRefGoogle Scholar
18.Jenekhe, S.A. and Chen, X.L., Science 283 (1999) p. 372.CrossRefGoogle Scholar
19.Srinivasarao, M., Collings, D., Philips, A., and Patel, S., Science 292 (2001) p. 79.CrossRefGoogle Scholar
20.Ishii, H., Sugiyama, K., Ito, E., and Seki, K., Adv. Mater. 11 (1999) p. 605.3.0.CO;2-Q>CrossRefGoogle Scholar
21.Veenstra, S.C., Stalmach, U., Krasnikov, V.V., Hadziioannou, G., Jonkman, H.T., Heeres, A., and Sawatzky, G.A., Appl. Phys. Lett. 76 (2000) p. 2253.CrossRefGoogle Scholar
22.Schön, J.H., Kloc, Ch., Bucher, E., and Batlogg, B., Nature 403 (2000) p. 408.CrossRefGoogle Scholar
23.Brabec, C.J., Sariciftci, N.S., and Hummelen, J.C., Adv. Funct. Mater. 11 (2001) p. 15.3.0.CO;2-A>CrossRefGoogle Scholar
24.de Boer, B., Stalmach, U., van Hutten, P.F., Melzer, C., Krasnikov, V.V., and Hadziioannou, G., Polymer 42 (2001) p. 9097.CrossRefGoogle Scholar