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Polymer–Fullerene Bulk Heterojunction Solar Cells

  • René A. J. Janssen, Jan C. Hummelen and N. Serdar Sariciftci


Nanostructured phase-separated blends, or bulk heterojunctions, of conjugated polymers and fullerene derivatives form a very attractive approach to large-area, solid-state organic solar cells. The key feature of these cells is that they combine easy processing from solution on a variety of substrates with good performance. Efficiencies of up to 5% in solar light have been achieved, and lifetimes are increasing to thousands of hours. Further improvements can be expected and some of the promising strategies towards that goal are presented in this article.



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1.Yu, G., Gao, J., Hummelen, J.C., Wudl, F., and Heeger, A.J., Science 270 (1995) p. 1789.
2.Halls, J.J.M., Walsh, C.A., Greenham, N.C., Marseglia, E.A., Friend, R.H., Moratti, S.C., and Holmes, A.B., Nature 376 (1995) p. 498.
3.Sariciftci, N.S., Smilowitz, L., Heeger, A.J., and Wudl, F., Science 258 (1992) p. 1474.
4.Brabec, C.J., Zerza, G., Cerullo, G., De Silvestri, S., Luzzati, S., Hummelen, J.C., and Sariciftci, N.S., Chem. Phys. Lett. 340 (2001) p. 232.
5.Montanari, I., Nogueira, A.F., Nelson, J., Durrant, J.R., Winder, C., Loi, M.A., Sariciftci, N.S., and Brabec, C.J., Appl. Phys. Lett. 81 (2002) p. 3001.
6.Offermans, T., Meskers, S.C.J., and Janssen, R.A.J., J. Chem. Phys. 119 (2003) p. 10467.
7.Shaheen, S.E., Brabec, C.J., Sariciftci, N.S., Padinger, F., Fromherz, T., and Hummelen, J.C., Appl. Phys. Lett. 78 (2001) p. 841.
8.van Duren, J.K.J., Yang, X.N., Loos, J., Bulle-Lieuwma, C.W.T., Sieval, A.B., Hummelen, J.C., and Janssen, R.A.J., Adv. Funct. Mater. 14 (2004) p. 425.
9.Martens, T., D'Haen, J., Munters, T., Beelen, Z., Goris, L., Manca, J., D'Olieslaeger, M., Vanderzande, D., De Schepper, L., and Andriessen, R., Synth. Met. 138 (2003) p. 243.
10.Michailetchi, V.D., Blom, P.W.M., Hummelen, J.C., and Rispens, M.T., J. Appl. Phys. 94 (2003) p. 6849.
11.Brabec, C.J., Cravino, A., Meissner, D., Sariciftci, N.S., Fromherz, T., Rispens, M.T., Sanchez, L., and Hummelen, J.C., Adv. Funct. Mater. 11 (2001) p. 374.
12.Mihailetchi, V.D., Koster, L.J.A., Blom, P.W.M., Appl. Phys. Lett. 85 (2004) p. 970.
13.Mihailetchi, V.D., van Duren, J.K.J., Blom, P.W.M., Hummelen, J.C., Janssen, R.A.J., Kroon, J.M., Rispens, M.T., Verhees, W.J.H., Wienk, M.M., Adv. Funct. Mater. 13 (2003) p. 43.
14.Padinger, F., Rittberger, R.S., and Sariciftci, N.S., Adv. Funct. Mater. 13 (2003) p. 85.
15.Schilinsky, P., Waldauf, C., and Brabec, C.J., Appl. Phys. Lett. 81 (2002) p. 3885.
16.Camaioni, N., Ridolfi, G., Casalbore-Miceli, G., Possamai, G., and Maggini, M., Adv. Mater. 14 (2002) p. 1735.
17.Ditmer, J.J., Marsegla, E.A., and Friend, R.H., Adv. Mater. 12 (2000) p. 1270.
18.Veenstra, S.C., Verhees, W.J.H., Kroon, J.M., Koetse, M.M., Sweelssen, J., Bastiaansen, J.J.A.M., Schoo, H.F.M., Yang, X., Alexeev, A., Loos, J., Schubert, U.S., and Wienk, M.M., Chem. Mater. 16 (2004) p. 2503.
19.Peumans, P., Uchida, S., and Forrest, S.R., Nature 425 (2003) p. 158.
20.Brabec, C.J., Sol. Energy Mater. Sol. Cells 83 (2004) p. 273.
21.Wienk, M.M., Kroon, J.M., Verhees, W.J.H., Knol, J., Hummelen, J.C., van Hal, P.A., and Janssen, R.A.J., Angew. Chem. Int. Ed. 42 (2003) p. 3371.
22.Schuller, S., Schilinsky, P., Hauch, J., and Brabec, C.J., Appl. Phys. A 79 (2004) p. 37.
23.Yang, X., Van Duren, J.K.J., Janssen, R.A.J., Michels, M.A.J., and Loos, J., Macromolecules 37 (2004) p. 2151.
24.Müller, C.D., Falcou, A., Reckefuss, N., Rojahn, M., Wiederhirn, V., Rudati, P., Frohne, H., Nuyken, O., Becker, H., and Meerholz, K., Nature 421 (2003) p. 829. Boer, B., Stalmach, U., van Hutten, P.F., Melzer, C., Krasnikov, V.V., and Hadziioannou, G., Polymer 42 (2001) p. 9097.
26.Svensson, M., Zhang, F., Veenstra, S.C., Verhees, W.J.H., Hummelen, J.C., Kroon, J.M., Inganäs, O., and Andersson, M.R., Adv. Mater. 15 (2003) p. 988.
27.Brabec, C.J., Winder, C., Sariciftci, N.S., Hummelen, J.C., Dhanabalan, A., van Hal, P.A., and Janssen, R.A.J., Adv. Funct. Mater. 12 (2002) p. 709.
28.Mozer, A.J., Denk, P., Scharber, M.C., Neugebauer, H., Sariciftci, N.S., Wagner, P., Lutsen, L., and Vanderzande, D., J. Phys. Chem. B 108 (2004) p. 5235.
29.Fairly, P., Technol. Rev. (July/August) (2004) p. 35.


Polymer–Fullerene Bulk Heterojunction Solar Cells

  • René A. J. Janssen, Jan C. Hummelen and N. Serdar Sariciftci


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