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Personal perspectives on graphene: New graphene-related materials on the horizon

  • Rodney S. Ruoff (a1)


In this article, I describe my early interest in graphene and contributions that I and my co-authors, in particular, have made to the field, along with a brief history of the experimental discovery of graphene. I then turn to new carbon materials whose experimental syntheses might be on the horizon. One example involves using graphene as a template to generate large-area ultrathin sp3-bonded carbon sheets that could also be substitutionally doped with, for example, nitrogen atoms, as one approach to making materials of interest for quantum computing. Such large-area sp3-bonded carbon sheets hold tremendous promise for use in thermal management; as a new material for electronics and photonics; and as ultrahigh-strength components in various structures including those used in aerospace, among other applications. Another example is the class of negative-curvature carbons (NCCs) that have atom-thick walls and carbon atoms trivalently bonded to other carbon atoms. Such NCCs have a nanoscale pore structure, atom-thick walls, and exceptionally high specific surface areas, and they fill three-dimensional space in ways that suggest their use as electrode materials for ultracapacitors and batteries, as adsorbents, as support material for catalysts, and for other applications.



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1.Iijima, S.Nature 354, 56 (1991).
2.Walker, G.F., Garret, W.G., Science 156 (3773), 385 (1967).
3.Norrish, K., Discuss. Faraday Soc. 18, 120 (1954).
4.“Vermiculite,” (accessed October 2012).
5.Fitzer, E., Kochling, K.-H., Boehm, H.P., Marsh, H., Eds., Pure Appl. Chem. 67 (3), 473 (1995).
6.Lu, X.K., Huang, H., Nemchuk, N., Ruoff, R.S., Appl. Phys. Lett. 75, 193 (1999).
7.Lu, X.K., Yu, M.F., Huang, H., Ruoff, R.S., Nanotechnology 10, 269 (1999).
8.Zhang, Y., Small, J.P., Pontius, W.V., Kim, P.Appl. Phys. Lett. 86, 073104 (2005).
9.Novoselov, K.S., Geim, A.K., Morosov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieva, I.V., Firsov, A.A., Science 306, 666 (2004).
10.Zhang, X., Lerner, M.M., Chem. Mater. 11 (4), 1100 (1999).
11.Zhang, X., Sukpirom, N., Lerner, M.M., Mater. Res. Bull. 34, 363 (1999).
12.Zhang, X., Lerner, M.M., Phys. Chem. Chem. Phys. 1, 5065 (1999).
13.Zhang, Z., Lerner, M.M., Chem. Mater. 8, 257 (1996).
14.Mohanty, N., Moore, D., Xu, Z., Sreeprasad, T.S., Nagaraja, A., Rodriguez, A.A., Berry, V., Nat. Commun. 3, 844 (2012).
15.Stankovich, S., Dikin, D.A., Dommett, G.H.B., Kohlhaas, K.M., Zimney, E.J., Stach, E.A., Piner, R.D., Nguyen, S.T., Ruoff, R.S., Nature 442, 282 (2006).
16.Dikin, D.A., Stankovich, S., Zimney, E.J., Piner, R.D., Dommett, G.H.B., Evmenenko, G., Nguyen, S.T., Ruoff, R.S., Nature 448, 457 (2007).
17.Watcharotone, S., Dikin, D.A., Stankovich, S., Piner, R., Jung, I., Dommett, G.H.B., Evmenenko, G., Wu, S.-E., Chen, S.-F., Liu, C.-P., Nguyen, S.T., Ruoff, R.S., Nano Lett. 7, 1888 (2007).
18.Jung, I., Pelton, M., Piner, R., Dikin, D.A., Stankovich, S., Watcharotone, S., Hausner, M., Ruoff, R.S., Nano Lett. 7, 3569 (2007).
19.Cai, W., Piner, R.D., Stadermann, F.J., Park, S., Shaibat, M.A., Ishii, Y., Yang, D., Velamakanni, A., An, S.J., Stoller, M., An, J., Chen, D., Ruoff, R.S., Science 321, 1815 (2008).
20.Jung, I., Dikin, D.A., Piner, R.D., Ruoff, R.S., Nano Lett. 8, 4283 (2008).
21.Park, S., An, J., Jung, I., Piner, R.D., An, S.J., Li, X., Velamakanni, A., Ruoff, R.S., Nano Lett. 9, 1593 (2009).
22.Stoller, M.D., Park, S., Zhu, Y., An, J., Ruoff, R.S., Nano Lett. 8, 3498 (2008).
23.Zhu, Y., Murali, S., Stoller, M.D., Ganesh, K.J., Cai, W., Ferreira, P.J., Pirkle, A., Wallace, R.M., Cychosz, K.A., Thommes, M., Su, D., Stach, E.A., Ruoff, R.S., Science 332, 1537 (2011).
24.Zhang, L.L., Zhao, X., Stoller, M.D., Zhu, Y., Ji, H., Murali, S., Wu, Y., Perales, S., Clevenger, B., Ruoff, R.S., Nano Lett. 12, 1806 (2012).
25.Stoller, M.D., Murali, S., Quarles, N., Zhu, Y., Potts, J.R., Zhu, X., Ha, H.-W., Ruoff, R.S., Phys. Chem. Chem. Phys. 14, 3388 (2012).
26.Li, X., Cai, W., An, J., Kim, S., Nah, J., Yang, D., Piner, R., Velamakanni, A., Jung, I., Tutuc, E., Banerjee, S.K., Colombo, L., Ruoff, R.S., Science 324, 1312 (2009).
27.Li, X., Cai, W., Colombo, L., Ruoff, R.S., Nano Lett. 9, 4268 (2009).
28.Li, X., Zhu, Y., Cai, W., Borysiak, M., Han, B., Chen, D., Piner, R.D., Colombo, L., Ruoff, R.S., Nano Lett. 9, 4359 (2009).
29.Li, X., Magnuson, C.W., Venugopal, A., An, J., Suk, J.W., Han, B., Borysiak, M., Cai, W., Velamakanni, A., Zhu, Y., Fu, L., Vogel, E.M., Voelkl, E., Colombo, L., Ruoff, R.S., Nano Lett. 10, 4328 (2010).
30.Li, X., Magnuson, C.W., Venugopal, A., Tromp, R.M., Hannon, J.B., Vogel, E.M., Colombo, L., Ruoff, R.S., J. Am. Chem. Soc. 133, 2816 (2011).
31.Chen, S., Wu, Q., Mishra, C., Kang, J., Zhang, H., Cho, K., Cai, W., Balandin, A.A., Ruoff, R.S., Nat. Mater. 11, 203 (2012).
32.Chen, S., Brown, L., Levendorf, M., Cai, W., Ju, S.-Y., Edgeworth, J., Li, X., Magnuson, C.W., Velamakanni, A., Piner, R.D., Kang, J., Park, J., Ruoff, R.S., ACS Nano 5, 1321 (2011).
33.Pantelic, R.S., Suk, J.W., Magnuson, C.W., Meyer, J.C., Wachsmuth, P., Kaiser, U., Ruoff, R.S., Stahlberg, H., J. Struct. Biol. 174, 234 (2011).
34.Pantelic, R.S., Suk, J.W., Hao, Y., Ruoff, R.S., Stahlberg, H., Nano Lett. 11, 4319 (2011).
35.Ruoff, R., Nat. Nanotechnol. 3, 10 (2008).
36.The Ruoff Group, Nanoscience and Technology Lab,
37.May, J.W.Surf. Sci. 17, 267 (1969).
38.Hagstrom, S., Lyon, H.B., Somorjai, G.A., Phys. Rev. Lett. 15, 491 (1965).
39.Lyon, H.B., Somorjai, G.A., J. Chem. Phys. 46, 2539 (1967).
40.Lyon, H.B., Matera, A.M., Somorjai, G.A., in Fundamentals of Gas–Surface Interactions, Saltsburg, H., Smith, J.M., Rogers, M., Eds. (Academic Press, New York, 1967), p. 102.
41.Morgan, A.E., Somorjai, G.A., Surf. Sci. 12, 405 (1968).
42.Fallahazad, B., Hao, Y., Lee, K., Kim, S., Ruoff, R.S., Tutuc, E., Phys. Rev. B 85, 201408(R) (2012).
43.Ruoff, R., Nature 483, S42 (2012).
44.Chernozatonskii, L., Sorokin, P., Kvashnin, A., Kvashnin, D., JETP Lett. 90, 134 (2009).
45.Leenaerts, O., Partoens, B., Peeters, F.M., Phys. Rev. B 80, 245422 (2009).
46.Zhu, L.Y., Hu, H., Chen, Q., Wang, S., Wang, J., Ding, F., Nanotechnology 22, 185202 (2011).
47.Chernozatonskii, L.A., Sorokin, P.B., Kuzubov, A.A., Sorokin, B.P., Kvashnin, A.G., Kvashnin, D.G., Avramov, P.V., Yakobson, B.I., J. Phys. Chem. C 115, 132 (2010).
48.Chernozatonskii, L.A., Mavrin, B.N., Sorokin, P.B., Phys. Status Solidi B 249, 1550 (2012).
49.Weber, J.R., Koehl, W.F., Varley, J.B., Janotti, A., Buckley, B.B., Van de Walle, C.G., Awschalom, D.D., Proc. Natl. Acad. Sci. U.S.A. 107, 8513 (2010).
50.Townsend, S.J., Lenosky, T.J., Muller, D.A., Nichols, C.S., Elser, V., Phys. Rev. Lett. 69, 921 (1992).
51.Terrones, H., Mackay, A.L., Prog. Cryst. Growth Charact. Mater. 34, 25 (1997).
52.Barborini, E., Piseri, P., Milani, P., Benedek, G., Ducati, C., Robertson, J., Appl. Phys. Lett. 81, 3359 (2002).
53.Park, S., Kittimanapun, K., Ahn, J.S., Kown, Y.K., Tomanek, D., J. Phys.: Condens. Matter 22 (3), 334220 (2010).
54.Park, N., Yoon, M., Berber, S., Ihm, J., Osawa, E., Tomanek, D., Phys. Rev. Lett. 91 (23), 237204 (2003).
55.Huang, M.-Z., Ching, W.Y., Lenofsky, T., Phys. Rev. B. 47 (3), 1593 (1993).
56.Terrones, H., Terrones, M., New J. Phys. 5, 126 (2003).



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