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Fulfilling Feynman’s dream: “Make the electron microscope 100 times better”—Are we there yet?

  • Stephen J. Pennycook (a1)

Abstract

In his famous 1959 lecture “There’s plenty of room at the bottom,” Richard Feynman put out this challenge: “Is there no way to make the electron microscope more powerful?” He called for “improving the electron microscope by a hundred times,” which, given that the resolution then was about 10 Å, meant he was calling for a resolution in the range of 0.1 Å. Today’s aberration-corrected microscopes have come a long way, achieving a resolution of around 0.5 Å. This has enormously improved our ability to see atomic arrangements in crystals, measure ferroelectric displacements, and even determine valence and spin states with electron energy-loss spectroscopy. However, there remain many structures crucial to materials properties that we cannot yet see. Continuing the road toward Feynman’s goal would bring these structures to light, with yet more dramatic impacts on the entire field of materials science.

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1.Feynman, R.P., J. Microelectromech. Syst. 1, 60 (1992).
2.Scherzer, O., Optik 2, 114 (1947).
3.Scherzer, O., Z. Phys. A: Hadrons Nucl. 101, 593 (1936).
4.Archard, G.D., Br. J. Appl. Phys. 5, 294 (1954).
5.Beck, V.D., Optik 53, 241 (1979).
6.Crewe, A.V., Kopf, D., Optik 55, 1 (1980).
7.Rose, H., Nucl. Instrum. Methods Phys. Res. 187, 187 (1981).
8.Krivanek, O.L., Dellby, N., Lupini, A.R., Ultramicroscopy 78, 1 (1999).
9.Zach, J., Haider, M., Nucl. Instrum. Methods Phys. Res., A 363, 316 (1995).
10.Uhlemann, S., Haider, M., Ultramicroscopy 72, 109 (1998).
11.Haider, M., Uhlemann, S., Schwan, E., Rose, H., Kabius, B., Urban, K., Nature 392, 768 (1998).
12.Haider, M., Rose, H., Uhlemann, S., Schwan, E., Kabius, B., Urban, K., Ultramicroscopy 75, 53 (1998).
13.Haider, M., Rose, H., Uhlemann, S., Kabius, B., Urban, K., J. Electron Microsc. 47, 395 (1998).
14.Dellby, N., Krivanek, O.L., Nellist, P.D., Batson, P.E., Lupini, A.R., Microscopy 50, 177 (2001).
15.Batson, P.E., Dellby, N., Krivanek, O.L., Nature 418, 617 (2002).
16.Nellist, P.D., Chisholm, M.F., Dellby, N., Krivanek, O.L., Murfitt, M.F., Szilagyi, Z.S., Lupini, A.R., Borisevich, A., Sides, W.H., Pennycook, S.J., Science 305, 1741 (2004).
17.Erni, R., Rossell, M.D., Kisielowski, C., Dahmen, U., Phys. Rev. Lett. 102, 96101 (2009).
18.Sawada, H., Tanishiro, Y., Ohashi, N., Tomita, T., Hosokawa, F., Kaneyama, T., Kondo, Y., Takayanagi, K., J. Electron Microsc. 58, 357 (2009).
19.Pennycook, S.J., Boatner, L.A., Nature 336, 565 (1988).
20.Pennycook, S.J., Jesson, D.E., Phys. Rev. Lett. 64, 938 (1990).
21.Pennycook, S.J., Jesson, D.E., Ultramicroscopy 37, 14 (1991).
22.Rayleigh, Lord, Philos. Mag. 42, 167 (1896).
23.Pennycook, S.J., MRS Bull. 37, 943 (2012).
24.Pennycook, S.J., Colliex, C., MRS Bull. 37, 13 (2012).
25.von Ardenne, M., Z. Phys. 109, 553 (1938).
26.Crewe, A.V., J. Appl. Phys. 36, 2605 (1965).
27.Crewe, A.V., Wall, J., Langmore, J., Science 168, 1338 (1970).
28.Lee, J., Zhou, W., Pennycook, S.J., Idrobo, J.-C., Pantelides, S.T., Nat. Commun. 4, 1650 (2013).
29.Zhou, W., Kapetanakis, M.D., Prange, M.P., Pantelides, S.T., Pennycook, S.J., Idrobo, J.-C., Phys. Rev. Lett. 109, 206803 (2012).
30.Pennycook, S.J., Kalinin, S.V., Nature, 515, 587 (2014).
31.Jia, C.L., Urban, K.W., Alexe, M., Hesse, D., Vrejoiu, I., Science 331, 1420 (2011).
32.Jia, C., Mi, S., Urban, K., Vrejoiu, I., Alexe, M., Hesse, D., Nat. Mater. 7, 57 (2008).
33.Jia, C.L., Mi, S.B., Faley, M., Poppe, U., Schubert, J., Urban, K., Phys. Rev. B: Condens. Matter 79, 081405 (2009).
34.Jia, C., Nagarajan, V., He, J., Houben, L., Zhao, T., Ramesh, R., Urban, K., Waser, R., Nat. Mater. 6, 64 (2007).
35.Urban, K.W., MRS Bull. 32, 946 (2007).
36.Urban, K., Science 321, 506 (2008).
37.Borisevich, A., Ovchinnikov, O.S., Chang, H.J., Oxley, M.P., Yu, P., Seidel, J., Eliseev, E.A., Morozovska, A.N., Ramesh, R., Pennycook, S.J., Kalinin, S.V., ACS Nano 4, 6071 (2010).
38.Borisevich, A.Y., Chang, H.J., Huijben, M., Oxley, M.P., Okamoto, S., Niranjan, M.K., Burton, J.D., Tsymbal, E.Y., Chu, Y.H., Yu, P., Ramesh, R., Kalinin, S.V., Pennycook, S.J., Phys. Rev. Lett. 105, 087204 (2010).
39.Kim, Y.-M., Kumar, A., Hatt, A., Morozovska, A.N., Tselev, A., Biegalski, M.D., Ivanov, I., Eliseev, E.A., Pennycook, S.J., Rondinelli, J.M., Kalinin, S.V., Borisevich, A.Y., Adv. Mater. 25, 2497 (2013).
40.Cantoni, C., Gazquez, J., Miletto Granozio, F., Oxley, M.P., Varela, M., Lupini, A.R., Pennycook, S.J., Aruta, C., di Uccio, U.S., Perna, P., Maccariello, D., Adv. Mater. 24, 3952 (2012).
41.Peng, Y., Oxley, M.P., Lupini, A.R., Chisholm, M.F., Pennycook, S.J., Microsc. Anal. 14, 36 (2008).
42.Abe, E., Pennycook, S.J., Tsai, A.P., Nature 421, 347 (2003).
43.Pennycook, T.J., McBride, J.R., Rosenthal, S.J., Pennycook, S.J., Pantelides, S.T., Nano Lett. 12, 3038 (2012).
44.Li, C., Poplawsky, J., Wu, Y., Lupini, A.R., Mouti, A., Leonard, D.N., Paudel, N., Jones, K., Yin, W., Al-Jassim, M., Yan, Y., Pennycook, S.J., Ultramicroscopy 134, 113 (2013).
45.van Benthem, K., Lupini, A.R., Kim, M., Baik, H.S., Doh, S., Lee, J.-H., Oxley, M.P., Findlay, S.D., Allen, L.J., Luck, J.T., Pennycook, S.J., Appl. Phys. Lett. 87, 034104 (2005).
46.van Benthem, K., Lupini, A.R., Oxley, M.P., Findlay, S.D., Allen, L.J., Pennycook, S.J., Ultramicroscopy 106, 1062 (2006).
47.Borisevich, A.Y., Lupini, A.R., Pennycook, S.J., Proc. Natl. Acad. Sci. U.S.A. 103, 3044 (2006).
48.Borisevich, A.Y., Lupini, A.R., Travaglini, S., Pennycook, S.J., Microscopy 55, 7 (2006).
49.Nellist, P.D., Behan, G., Kirkland, A.I., Hetherington, C.J.D., Appl. Phys. Lett. 89, 124105 (2006).
50.Behan, G., Cosgriff, E.C., Kirkland, A.I., Nellist, P.D., Philos. Trans. R. Soc. Lon. A 367, 3825 (2009).
51.LeBeau, J.M., Findlay, S.D., Allen, L.J., Stemmer, S., Phys. Rev. Lett. 100, 206101 (2008).
52.Lebeau, J.M., D’alfonso, A., Findlay, S.D., Stemmer, S., Allen, L., Phys. Rev. B: Condens. Matter 80, 174106 (2009).
53.LeBeau, J.M., Findlay, S.D., Allen, L.J., Stemmer, S., Nano Lett. 10, 4405 (2010).
54.Ishikawa, R., Lupini, A.R., Findlay, S.D., Taniguchi, T., Pennycook, S.J., Nano Lett. 14, 1903 (2014).
55.De Backer, A., Martinez, G.T., Rosenauer, A., Van Aert, S., Ultramicroscopy 134, 23 (2013).
56.Van Aert, S., De Backer, A., Martinez, G., Goris, B., Bals, S., Van Tendeloo, G., Rosenauer, A., Phys. Rev. B: Condens. Matter 87, 064107 (2013).
57.Van Aert, S., Batenburg, K.J., Rossell, M.D., Erni, R., Van Tendeloo, G., Nature 470, 374 (2012).
58.Bals, S., Casavola, M., Van Huis, M.A., Van Aert, S., Batenburg, K.J., Van Tendeloo, G., Vanmaekelbergh, D., Nano Lett. 11, 3420 (2011).
59.Bals, S., Goris, B., Altantzis, T., Heidari, H., Van Aert, S., Van Tendeloo, G., C.R. Phys. 15, 140 (2014).
60.Goris, B., De Backer, A., Van Aert, S., Gómez-Graña, S., Liz-Marzan, L.M., Van Tendeloo, G., Bals, S., Nano Lett. 13, 4236 (2013).
61.Hwang, J., Zhang, J., D’Alfonso, A., Allen, L., Stemmer, S., Phys. Rev. Lett. 111, 266101 (2013).
62.Nellist, P.D., Pennycook, S.J., Science 274, 413 (1996).
63.Sohlberg, K., Rashkeev, S., Borisevich, A.Y., Pennycook, S.J., Pantelides, S.T., ChemPhysChem 5, 1893 (2004).
64.Lee, J., Yang, Z., Zhou, W., Pennycook, S.J., Pantelides, S.T., Chisholm, M.F., Proc. Natl. Acad. Sci. U.S.A. 111, 7522 (2014).
65.He, J., Borisevich, A., Kalinin, S.V., Pennycook, S.J., Pantelides, S.T., Phys. Rev. Lett. 105, 227203 (2010).
66.Varela, M., Lupini, A.R., Benthem, K.V., Borisevich, A.Y., Chisholm, M.F., Shibata, N., Abe, E., Pennycook, S.J., Annu. Rev. Mater. Res. 35, 539 (2005).

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