Hostname: page-component-8448b6f56d-sxzjt Total loading time: 0 Render date: 2024-04-23T18:53:41.667Z Has data issue: false hasContentIssue false
  • English
  • Français

Thermally-Induced Actuation of Magnetic Nanocomposites Based on Oligo(ω-Pentadecalactone) and Covalently Integrated Magnetic Nanoparticles

Published online by Cambridge University Press:  15 November 2018

M. Yasar Razzaq ,
M. Behl  and
A. Lendlein
M. Yasar Razzaq
Affiliation:
Institute of Biomaterial Science, Helmholtz-Zentrum Geesthacht, Kantstr. 55, 14513 Teltow, Germany
M. Behl
Affiliation:
Institute of Biomaterial Science, Helmholtz-Zentrum Geesthacht, Kantstr. 55, 14513 Teltow, Germany
A. Lendlein*
Affiliation:
Institute of Biomaterial Science, Helmholtz-Zentrum Geesthacht, Kantstr. 55, 14513 Teltow, Germany Institute of Chemistry, University of Potsdam, Karl-Liebknecht-Str. 24-25, 14476 Potsdam, Germany
*
*(Email: lendlein@uni-potsdam.de)
Get access

Abstract

The incorporation of inorganic particles in a polymer matrix has been established as a method to adjust the mechanical performance of composite materials. We report on the influence of covalent integration of magnetic nanoparticles (MNP) on the actuation behavior and mechanical performance of hybrid nanocomposite (H-NC) based shape-memory polymer actuators (SMPA). The H-NC were synthesized by reacting two types of oligo(ω-pentadecalactone) (OPDL) based precursors with terminal hydroxy groups, a three arm OPDL (3AOPDL, Mn = 6000 g mol·1-1) and an OPDL (Mn =3300 g · mol-1) coated magnetite nanoparticle (Ø = 10 ± 2 nm), with a diisocyanate. These H-NC were compared to the homopolymer network regarding the actuation performance, contractual stress (σcontr) as well as thermal and mechanical properties. The melting range of the OPDL crystals (ΔTm,OPDL) was shifted in homo polymer networks from 36 °C – 76 °C to 41°C – 81 °C for H-NC with 9 wt% of MNP content. The actuators were explored by variation of separating temperature (Tsep), which splits the OPDL crystalline domain into actuating and geometry determining segments. Tsep was varied in the melting range of the nanocomposites and the actuation capability and contractual stress (σcontr) of the nanocomposite actuators could be adjusted. The reversible strain (εrev) was decreased from 11 ± 0.3% for homo polymer network to 3.2±0.3% for H-NC9 with 9 wt% of MNP indicating a restraining effect of the MNP on chain mobility. The results show that the performance of H-NCs in terms of thermal and elastic properties can be tailored by MNP content, however for higher reversible actuation, lower MNP contents are preferable.

Keywords

actuationcompositecrystallization
Type
Articles
Information
MRS Advances , Volume 3 , Issue 63: International Materials Research Congress XXVII , 2018 , pp. 3783 - 3791
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Lochmatter, P., Kovacs, G. and Ermanni, P., Smart Materials & Structures 16 (4), 1415-1422 (2007).CrossRefGoogle Scholar
Shintake, J., Rosset, S., Schubert, B., Floreano, D. and Shea, H., Adv Mater 28 (2), 231-238 (2016).CrossRefGoogle Scholar
Wang, W., Wang, X. Z., Cheng, F. T., Yu, Y. L. and Zhu, Y. T., Prog Chem 23 (6), 1165-1173 (2011).Google Scholar
Zhao, Q., Yang, X. X., Ma, C. X., Chen, D., Bai, H., Li, T. F., Yang, W. and Xie, T., Materials Horizons 3 (5), 422-428 (2016).CrossRefGoogle Scholar
Gao, L., Guo, G. Q., Liu, M. J., Tang, Z. G., Xie, L. X. and Huo, Y. P., Rsc Adv 7 (63), 40005-40014 (2017).CrossRefGoogle Scholar
Li, X., Cai, X. B., Gao, Y. F. and Serpe, M. J., J Mater Chem B 5 (15), 2804-2812 (2017).CrossRefGoogle Scholar
Wang, J. R., Wang, J. F., Chen, Z., Fang, S. L., Zhu, Y., Baughman, R. H. and Jiang, L., Chem Mater 29 (22), 9793-9801 (2017).CrossRefGoogle Scholar
Jiang, H. R., Li, C. S. and Huang, X. Z., Nanoscale 5 (12), 5225-5240 (2013).CrossRefGoogle Scholar
Ohm, C., Brehmer, M. and Zentel, R., Adv Mater 22 (31), 3366-3387 (2010).CrossRefGoogle Scholar
Yu, Y. L., Abstr Pap Am Chem S 245 (2013).Google Scholar
Uh, K., Yoon, B., Lee, C. W. and Kim, J. M., ACS Appl Mater Inter 8 (2), 1289-1296 (2016).CrossRefGoogle Scholar
Wang, X. L., Oh, I. K. and Cheng, T. H., Polym Int 59 (3), 305-312 (2010).CrossRefGoogle Scholar
Festin, N., Plesse, C., Pirim, P., Chevrot, C. and Vidal, F., Sensor Actuat B-Chem 193, 82-88 (2014).CrossRefGoogle Scholar
Lee, E. H., Kim, H. M., Lim, S. K., Kim, K. S. and Chin, I. J., Mol Cryst Liq Cryst 492, 11-19 (2008).Google Scholar
Behl, M., Kratz, K., Noechel, U., Sauter, T. and Lendlein, A., P Natl Acad Sci USA 110 (31), 12555-12559 (2013).CrossRefGoogle Scholar
Biswas, A., Aswal, V. K., Sastry, P. U., Rana, D. and Maiti, P., Macromolecules 49 (13), 4889-4897 (2016).CrossRefGoogle Scholar
Farhan, M., Rudolph, T., Nochel, U., Yan, W., Kratz, K. and Lendlein, A., ACS Appl Mater Inter 9 (39), 33559-33564 (2017).CrossRefGoogle Scholar
Ge, F. J., Lu, X. L., Xiang, J., Tong, X. and Zhao, Y., Angew Chem Int Edit 56 (22), 6126-6130 (2017).CrossRefGoogle Scholar
Fuhrer, R., Athanassiou, E. K., Luechinger, N. A. and Stark, W. J., Small 5 (3), 383-388 (2009).CrossRefGoogle Scholar
Sommertune, J., Sugunan, A., Ahniyaz, A., Bejhed, R., Sarwe, A., Johansson, C., Balceris, C., Ludwig, F., Posth, O. and Fornara, A., International Journal of Molecular Sciences 16 (8), 19752 (2015).CrossRefGoogle Scholar
Razzaq, M. Y., Behl, M. and Lendlein, A., Nanoscale 4 (20), 6181-6195 (2012).CrossRefGoogle Scholar
Thevenot, J., Oliveira, H., Sandre, O. and Lecommandoux, S., Chem Soc Rev 42 (17), 7099-7116 (2013).CrossRefGoogle Scholar
Razzaq, M. Y., Behl, M., Kratz, K. and Lendlein, A., Adv Mater 25 (40), 5730-+ (2013).CrossRefGoogle Scholar
Wang, L., Razzaq, M. Y., Rudolph, T., Heuchel, M., Nöchel, U., Mansfeld, U., Jiang, Y., Gould, O. E. C., Behl, M., Kratz, K. and Lendlein, A., Materials Horizons 5, 861-867 (2018).CrossRefGoogle Scholar
Razzaq, M. Y., Behl, M., Frank, U., Koetz, J., Szczerba, W. and Lendlein, A., J Mater Chem 22 (18), 9237-9243 (2012).CrossRefGoogle Scholar
Razzaq, M. Y., Behl, M., Nochel, U. and Lendlein, A., Polymer 55 (23), 5953-5960 (2014).CrossRefGoogle Scholar
Behl, M., Kratz, K., Zotzmann, J., Nochel, U. and Lendlein, A., Adv Mater 25 (32), 4466-4469 (2013).CrossRefGoogle Scholar