Hostname: page-component-848d4c4894-jbqgn Total loading time: 0 Render date: 2024-06-24T15:07:17.085Z Has data issue: false hasContentIssue false

Theoretical Investigations Of Interfacial Scattering Effects On Thermoelectric Properties Of Bulk Nanostructured PbTe System

Published online by Cambridge University Press:  15 January 2018

Neeleshwar Sonnathi*
Affiliation:
Guru Gobind Singh Indraprastha University, New Delhi, India.
Anjali Panwar
Affiliation:
Guru Gobind Singh Indraprastha University, New Delhi, India.
Vikas Malik
Affiliation:
Jaypee Institue of Information Technology, Noida , UP, India
Anjana Bagga
Affiliation:
Guru Gobind Singh Indraprastha University, New Delhi, India.
Get access

Abstract

Enhancement of thermoelectric properties at room temperature has been recently demonstrated by spark plasma sintered PbTe nanocubes as compared to other PbTe nanostructures as well as Bulk material. The Seebeck coefficient has been reported to be 400 µV/K which is much higher than the bulk. Moreover, a moderate electrical conductivity ∼ 8000 S/m at room temperature results in considerable higher value of power factor S2σ ∼ 1.28 x 10-3 Wm-1K-2. The enhanced thermoelectric properties have been conjectured to be present due to energy filtering effects at numerous interfaces introduced by nanostructuring. We study how the interfacial scattering affects the power factor by performing theoretical modelling based on Boltzmann Transport Equation (BTE). We also investigate in detail, the role of various electronic parameters such as size, shape, mobility and effective mass etc., on interfacial scattering to optimize its effect on power factor.

Type
Articles
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Harman, T. C., Walsh, M. P., Laforge, B. E. and Turner, G. W., J. Elecron. Mater. 34, L19 (2005).Google Scholar
Martin, J., Nolas, G. S., Zhang, W., and Chen, L., Appl. Phys. Lett. 90, 222112 (2007).Google Scholar
Vinesis, C. J., Harman, T. C., Calawa, S. D., Walsh, M. P., Reeder, R. E., Singh, R., and Shakouri, A., Phys. Rev. B 77, 235202 (2008).Google Scholar
Bahk, Je-Hyeong, Bian, Zhixi, Shakouri, Ali, Phys. Rev. B 87, 075204 (2013).Google Scholar
Popescu, A., Woods, L. M., Martin, J., and Nolas, G.S., Phys. Rev. B 79, 205302 (2009).Google Scholar
Nishio, Y. and Hirano, T., Proceedings ICT98, 17th International Conference in Thermoelectrics, Nagoya, Japan, p. 111114, (1998).Google Scholar
Zeittili, N., Quantum Mechanics: Concepts and Applications (Wiley, Chichester, 2001).Google Scholar
Khasimsaheb, B., Neeleshwar, S., Srikanth, M., Bathula, S., Gahtori, B., Srivsatava, A. K., Dhar, A, Sankarakumar, A., Panigrahi, B. K., Bhattacharya, S., J. Mater. Res., 30, 26382648 (2015).Google Scholar